Catechol Lignosulfonate Microcapsules for Sunscreen

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Solution Overview

Problem

Existing lignin-based sunscreen creams face issues with skin penetration due to small particle size and poor bio-adhesion, and lignosulfonate's limited UV absorption and stability, leading to inadequate protection and application challenges.

Innovation Solution

A method to modify lignosulfonate through sulfidation to increase phenolic hydroxyl groups, forming catechol lignosulfonate microcapsules with improved bio-adhesion and stability, using a mild reaction process to encapsulate sunscreen agents, enhancing UV protection and skin compatibility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If lignin-based sunscreen creams are used, then UV protection is provided, but skin penetration occurs due to small particle size and poor bio-adhesion

Engineering Contradiction:
ImproveUV protectionVSAvoidskin penetration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical structure of lignin by introducing catechol groups through sulfidation reaction, changing the functional groups from methoxy to phenolic hydroxyl. This parameter change enhances bio-adhesion to skin while maintaining UV protection capability, preventing skin penetration without compromising protective function

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by combining modified lignin (catechol lignin) with sunscreen agents to form microcapsules. This composite material integrates the UV protection of lignin with the protective encapsulation of microcapsules, achieving both UV blocking and prevention of skin penetration

Inventive Principle:
Principle #40Composite materials

2Reliability

If lignosulfonate is used as sunscreen agent, then chemical sunscreen protection is provided, but UV absorption and stability are limited

Engineering Contradiction:
Improvesunscreen protectionVSAvoidUV absorption and stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent chemically modifies lignosulfonate by performing sulfidation reaction to convert methoxy groups into phenolic hydroxyl groups (catechol structure). This parameter change significantly enhances UV absorption capability and oxidative stability, transforming the limited performance of ordinary lignosulfonate into an effective sunscreen agent

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the phenolic hydroxyl groups introduced through sulfidation to enhance antioxidant activity. The catechol structure acts as a strong antioxidant that can scavenge free radicals and protect against oxidative damage, thereby improving the stability and UV absorption properties of the sunscreen formulation

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Data Source

PatentUS20240315943A1Light-colored catechol lignosulfonate sunscreen microcapsule, and preparation therefor and use thereof
Publication Date: 2024.09.26 SOUTH CHINA UNIV OF TECH
  • US20240315943A1 patent drawing
  • US20240315943A1 patent drawing
  • US20240315943A1 patent drawing

AI summary

Disclosed in the present invention are a light-colored catechol lignosulfonate sunscreen microcapsule, and a preparation therefor and the use thereof. According to the present invention, lignosulfonate is modified by using a vulcanization method to prepare catechol lignosulfonate, and the catechol lignosulfonate, a sunscreen agent and a surfactant are then subjected to ultrasonic cavitation to prepare a catechol lignosulfonate/chemical sunscreen agent microcapsule emulsion, The preparation process of the lignin/chemical sunscreen agent microcapsule of the present invention is environmentally friendly, has low costs and an excellent ultraviolet absorption performance, has a lighter color compared to other lignin-based sunscreen agents, and has a good biological adhesion and penetration resistance, which solves the problems of poor water resistance, greater pollution caused by the preparation process, easy penetration into the skin to harm the human body, etc. of conventional sunscreen agents.