Cathode Cushioning Section for High-Rolling Electrode Integrity
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Solution Overview
Problem
During the rolling process of secondary battery electrodes, high rolling ratios can lead to wrinkles and fractures due to the elongation difference between the coating and non-coating sections of the cathode collector, resulting in reduced productivity and electrode quality.
Innovation Solution
The cathode structure includes a coating section with a uniform thickness, a non-coating section, and a cushioning section with a thickness smaller than the coating section, positioned between the coating and non-coating sections to minimize elongation differences and prevent fractures.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Use of energy by moving object
If high rolling ratio is applied to manufacture secondary battery with high energy density, then energy density is improved, but wrinkles and fractures occur due to elongation difference between coating and non-coating sections
Solution Approach 1:
The cathode collector is divided into three distinct sections along the longitudinal direction: a coating section with uniform cathode mixture layer, a non-coating section without cathode mixture layer, and a cushioning section with gradually decreasing cathode mixture layer thickness. This segmentation allows each section to have different mechanical properties, with the cushioning section specifically designed to reduce elongation difference between the coating and non-coating sections during rolling, thereby preventing wrinkles and fractures while maintaining high energy density
Solution Approach 2:
The cushioning section is designed with locally varying cathode mixture layer thickness that gradually decreases from the coating section toward the non-coating section. This local quality variation creates a gradient structure that smoothly transitions the mechanical properties between sections, reducing stress concentration and elongation difference at the transition zones during the rolling process
2Reliability
If IHA heating is used to soften the non-coating section to reduce elongation difference, then wrinkle formation is reduced, but collector quality deteriorates due to excessive softening
Solution Approach 1:
The cathode mixture layer is applied with a pre-designed thickness gradient in the cushioning section before the rolling process begins. This preliminary action creates a built-in compensation mechanism where the varying thickness of the cathode mixture layer pre-adjusts the elongation characteristics of different sections during rolling, eliminating the need for post-application IHA heating and avoiding excessive softening of the collector
Solution Approach 2:
The invention replaces the thermal field approach (IHA heating) with a structural field approach (cathode mixture layer thickness gradient). Instead of using heat to modify the mechanical properties of the non-coating section, the cushioning section uses the varying thickness of the cathode mixture layer to mechanically compensate for elongation differences during rolling, achieving the same effect without thermal intervention
3Ease of manufacture
If uniform cathode mixture layer thickness is applied across the entire collector, then manufacturing simplicity is maintained, but elongation difference between coating and non-coating sections causes fractures during rolling
Solution Approach 1:
The cathode mixture layer is designed with different thickness characteristics in different sections: uniform thickness in the coating section for simplicity, and gradually decreasing thickness in the cushioning section toward the non-coating section. This local quality differentiation maintains manufacturing simplicity in the main coating area while introducing the necessary thickness variation only in the cushioning section to prevent fractures during rolling
Data Source
AI summary
Proposed is a cathode for a secondary battery, which includes a cathode collector and a cathode mixture layer on the cathode collector, includes: a coating section at which the cathode mixture layer is formed with a uniform thickness; a non-coating section that is disposed on at least one edge of the coating section on the cathode collector and at which the cathode mixture layer is not formed; and a cushioning section at which the cathode mixture layer is formed with a thickness smaller than a thickness of the coating section at a location between the coating section and the non-coating section.


