Cation Exchange Chromatography for Allergen Removal

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Solution Overview

Problem

The molecular origin of allergy in mammals remains unclear, with known allergens often being harmless to most individuals, and existing methods fail to effectively reduce allergenicity in food and pharmaceutical compositions.

Innovation Solution

The method involves treating compositions using cation exchange and/or affinity chromatography to remove cationic proteins resulting from transcription infidelity (TI) events, which are enriched in basic amino acids and have a modified C-terminal end, thereby reducing allergenicity by removing at least 50% of proteins with an isoelectric point above 7.4.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional methods are used to process food and pharmaceutical compositions, then the compositions retain their full protein content and nutritional/pharmaceutical value, but they maintain allergenicity due to the presence of cationic proteins resulting from transcription infidelity

Engineering Contradiction:
ImproveallergenenicityVSAvoidprotein content
Core Design Contradiction:
Object-affected harmful factorsVSQuantity of substance

Solution Approach 1:

The patent applies extraction by removing cationic proteins from compositions through cation exchange chromatography. The method specifically extracts proteins with pI > 7.4 that result from transcription infidelity, separating them from the bulk protein content while retaining nutritional and pharmaceutical components

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent utilizes parameter changes by exploiting the isoelectric point (pI) difference between cationic allergenic proteins and other proteins. By adjusting pH conditions during cation exchange chromatography, the method selectively binds and removes proteins with pI > 7.4, changing the electrical charge state to achieve separation

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If cation exchange chromatography is used to remove cationic proteins, then allergenicity is reduced by removing at least 50% of proteins with isoelectric point above 7.4, but the process complexity and manufacturing steps increase

Engineering Contradiction:
ImproveallergenenicityVSAvoidprocess complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The method changes pH parameters to control protein charge states, enabling selective binding of cationic proteins to the cation exchange resin. By adjusting pH below the isoelectric point of target proteins, they acquire positive charge and bind to the negatively charged resin, while other proteins pass through

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The cation exchange resin acts as an intermediary medium that facilitates selective removal of cationic proteins. The resin provides a charged surface that temporarily binds target proteins, allowing separation without direct manipulation of the protein molecules themselves

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If affinity chromatography is used to remove cationic proteins, then allergenicity is reduced with high specificity, but the manufacturing cost and process complexity increase

Engineering Contradiction:
ImproveallergenenicityVSAvoidmanufacturing cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

Affinity ligands are used as intermediaries that specifically recognize and bind to cationic proteins resulting from transcription infidelity. These ligands are immobilized on chromatography matrices, creating a selective capture system that removes allergens with high specificity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The affinity chromatography method extracts specific cationic allergenic proteins from compositions by exploiting unique molecular recognition interactions. The targeted proteins are selectively bound and removed, leaving the majority of protein content intact

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces allergenicity by eliminating proteins that trigger IgE production, making compositions hypoallergenic and less immunogenic, as demonstrated by the removal of TI gap proteins from milk and peanut products, which significantly decreases IgE induction in murine models.

Implementation Method 1

treating the composition by cation exchange and/or affinity chromatography to remove cationic proteins

Methodology Applied
Scientific EffectCation exchange: Ion Exchange

Implementation Method 2

treating the composition by cation exchange and/or affinity chromatography to remove cationic proteins

Methodology Applied
Scientific EffectAffinity chromatography: Adsorption

Data Source

PatentEP3430390B1Molecular origin of allergy
Publication Date: 2022.08.03 GENCLIS
  • EP3430390B1 patent drawingFigure 1
  • EP3430390B1 patent drawingFigure 2
  • EP3430390B1 patent drawingFigure 3

AI summary

The present invention relates to compositions and methods for modulating or detecting allergy in a subject. The invention may be used to reduce allergenicity of compositions, such as food products, or to stimulate immunogenicity of products, such as vaccines. The invention may be used in any mammal such as human.