Cationic Anionic Polymer Hair Cosmetic for Wet Combability

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Solution Overview

Problem

Conventional hair cosmetics fail to adequately improve the feel and appearance of damaged hair, particularly in enhancing finger combability of wet hair and manageability of dried hair, and often lose effectiveness with repeated washing.

Innovation Solution

A hair cosmetic comprising a cationic polymer with a charge density of 5.0 meq/g to 7.0 meq/g and an anionic polymer comprising 80% to 100% of a specific constitutional unit, which are used in a two-part or three-part hair bleach or dye composition to improve hair durability and retention of conditioning effects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional conditioning components are applied to hair, then initial conditioning effect is achieved, but the effect is not retained after repeated washing

Engineering Contradiction:
Improveretention of conditioning effectVSAvoidduration of conditioning effect
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent applies parameter changes by specifying precise molecular weight ranges (10,000-100,000 for cationic polymer, 50,000-500,000 for anionic polymer) and charge density parameters to optimize the conditioning effect retention. This resolves the contradiction by finding the optimal parameter window where both initial effectiveness and long-term retention are achieved.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining specific cationic polymers with specific anionic polymers in defined ratios. This composite approach creates a synergistic effect where the cationic polymer adsorbs onto damaged hair regions and the anionic polymer enhances retention, solving the problem of effect loss after repeated washing.

Inventive Principle:
Principle #40Composite materials

2Reliability

If hair bleach or dye compositions are used, then hair color treatment is achieved, but hair entanglement and deterioration in feel occur

Engineering Contradiction:
Improvecolor treatment effectivenessVSAvoidhair entanglement and damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces polymer complexes as intermediaries between the harsh bleach/dye chemicals and the hair structure. These polymer complexes (formed by cationic and anionic polymers) act as protective mediators that reduce direct chemical damage and physical entanglement while allowing color treatment to proceed effectively.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the potentially harmful interaction between oppositely charged polymers (which could cause precipitation) into a beneficial effect by controlling the molecular weights and charge densities to form stable, beneficial polymer complexes that condition and protect hair during chemical treatment.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of operation

If cationic and anionic polymers are combined to enhance hair gloss and softness, then conditioning effect is improved, but hair entanglement may occur during washing

Engineering Contradiction:
Improvehair manageabilityVSAvoidhair entanglement during washing
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent resolves this contradiction through precise parameter control: limiting cationic polymer molecular weight to 10,000-100,000 and anionic polymer to 50,000-500,000, and controlling charge densities. These parameter restrictions prevent excessive polymer-polymer interactions that would cause entanglement while maintaining sufficient conditioning effectiveness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly enhances the feel and appearance of damaged hair by improving finger combability and manageability, maintaining these effects even after repeated washing, and providing long-lasting hair gloss and softness.

Implementation Method 1

a technique for increasing the adsorption amount of silicones by using a specific cationic polymer together with an amino-modified silicone and a highly polymerized silicone

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a hair cosmetic containing a specific cationic polymer and a specific anionic polymer can solve the above-described problems all at once

Methodology Applied
Scientific EffectElectrostatic attraction: Ion Repulsion/Attraction

Data Source

PatentEP3108872B2Hair cosmetic
Publication Date: 2021.09.15 KAO CORP
  • EP3108872B2 patent drawing
  • EP3108872B2 patent drawing
  • EP3108872B2 patent drawing

AI summary

A hair cosmetic containing Components (A) and (B): (A) a cationic polymer having a charge density of 5.0 to 7.0 meq/g; and (B) an anionic polymer comprising 80% by mass or more and 100% by mass or less of a constitutional unit represented by Formula (1) and having a weight-average molecular weight of 4,000 or more and 80,000 or less, where R1 represents a hydrogen atom or a carboxy group; and R2 represents a hydrogen atom or a methyl group.