Cationic Azo Dyes for Oxidative Hair Coloring

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Solution Overview

Problem

Existing hair dye technologies face challenges with nonoxidative colorants, which have lower durability and uneven color distribution, and are unable to lighten hair due to instability under oxidative conditions.

Innovation Solution

Development of cationic azodyes with a specific formula that are oxidation-stable, allowing for intense and durable coloring of keratin fibers, including the ability to lighten hair when used in oxidative systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If nonoxidative colorants are used, then the coloring process is gentle and causes low damage to keratin fibers, but the durability and evenness of color are lower

Engineering Contradiction:
Improvedamage to keratin fibersVSAvoiddurability and evenness of color
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the colorant by developing cationic azo dyes with specific molecular structures (formula I) that possess oxidation stability. This allows the dye to function effectively in oxidative systems while maintaining fiber compatibility, thereby improving color durability and evenness without excessive damage to keratin fibers.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coloring system that combines cationic azo dyes with oxidative agents. This composite approach enables the dye to benefit from both the gentleness of nonoxidative methods and the durability of oxidative methods, achieving a balance between fiber protection and color performance.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If direct dyes are used for nonoxidative coloring, then the process is easy to use and gentle on fibers, but the colorants cannot lighten hair due to instability under oxidative conditions

Engineering Contradiction:
Improveease of useVSAvoidability to lighten hair
Core Design Contradiction:
Ease of operationVSAdaptability or versatility

Solution Approach 1:

The patent modifies the chemical parameters of azo dyes by introducing cationic groups and specific heterocyclic structures that confer oxidation stability. This enables the dye to withstand oxidative conditions required for lightening, expanding its versatility while maintaining ease of application.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The cationic azo dyes of formula (I) are designed to perform multiple functions: they can be used in both nonoxidative and oxidative coloring systems, and can achieve both coloring and lightening effects. This multi-functionality eliminates the need for separate dye systems for different hair treatment goals.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Quantity of substance

If cationic azo dyes with localized charge are used for synthetic fibres, then the dyeing effect is achieved, but they cannot be used for keratin fibers requiring oxidation stability

Engineering Contradiction:
Improvedyeing effectivenessVSAvoidoxidation stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent fundamentally changes the chemical parameters of cationic azo dyes by delocalizing the positive charge throughout the conjugated system rather than localizing it in side chains. This structural modification confers oxidation stability while maintaining effective dyeing of keratin fibers, bridging the gap between synthetic fiber dyes and hair coloring requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cationic azodyes provide strong, even color with good durability and mildness to hair, enabling both coloring and lightening capabilities in oxidative systems.

Implementation Method 1

colorants which comprise cationic azo dyes, in which the positive charge is delocalised in the conjugated system

Methodology Applied
Scientific EffectElectrostatic attraction: Ion Repulsion/Attraction

Implementation Method 2

an agent for the simultaneous lightening and coloring of keratin fibers, in particular human hair, which, besides the dye of the formula (I), comprises an oxidizing agent

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS7658771B2Coloring agents for keratin fibers
Publication Date: 2010.02.09 WELLA OPERATIONS US LLC
  • US7658771B2 patent drawing
  • US7658771B2 patent drawing
  • US7658771B2 patent drawing

AI summary

The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).