Cationic Deposition Polymers for Fabric Care Agent Transfer

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Solution Overview

Problem

Current laundry detergent compositions face challenges in achieving efficient deposition of fabric care agents onto fabrics during laundering, as most agents remain in the wash liquor due to incompatibility with detersive enzymes and anionic surfactants, leading to instability and reduced fabric care benefits.

Innovation Solution

The development of a laundry detergent composition that includes non-polysaccharide based cationic deposition polymers, fabric care benefit agents, and surfactants, which are compatible and stable, allowing for enhanced deposition of fabric care agents onto fabrics while maintaining effective cleaning capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cationic polysaccharide-based polymers are used as deposition aids, then deposition of fabric care agents is enhanced, but compatibility with detersive enzymes is lost

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidenzyme compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the chemical composition parameters of the deposition aid by switching from natural polysaccharides to synthetic polymers with specific cationic functional groups (ammonium, quaternary ammonium, or amine groups). This parameter change maintains deposition effectiveness while eliminating enzyme incompatibility, as the synthetic polymers can be formulated to be enzyme-stable.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite polymer structures combining cationic functional groups with hydrophobic or hydrophilic side chains to create deposition aids that simultaneously achieve effective fabric care agent deposition and enzyme compatibility. The composite nature allows optimization of both deposition performance and stability with detergent components.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If synthetic cationic polymers are used to avoid enzyme degradation, then enzyme compatibility is improved, but compatibility with anionic surfactants is lost

Engineering Contradiction:
Improveenzyme compatibilityVSAvoidformulation stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent modifies the chemical parameters of cationic polymers by controlling the ratio and type of cationic functional groups to anionic surfactant interaction. By adjusting the charge density and specific functional group composition, the polymer maintains enzyme stability while reducing strong interactions with anionic surfactants that cause precipitation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces nonionic or zwitterionic polymers as intermediary substances that mediate between cationic deposition aids and anionic surfactants. These intermediary polymers reduce the harmful interactions between cationic polymers and anionic surfactants, preventing precipitation while maintaining deposition effectiveness.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If deposition aids are added to enhance fabric care agent deposition, then deposition efficiency is improved, but formulation stability is reduced

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidformulation stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent optimizes formulation stability by carefully controlling the concentration parameters and chemical composition of deposition aids. By adjusting the amount of cationic polymer and its molecular weight distribution, the formulation maintains stability during storage while achieving effective deposition during the laundering cycle.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary stabilization of the deposition aid through pre-formulation techniques, such as cross-linking or complexation with stabilizing agents, before incorporation into the detergent. This preliminary action prevents premature aggregation or degradation of the deposition aid, maintaining formulation stability throughout the product lifecycle.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved deposition of fabric care agents onto fabrics, providing superior cleaning and fabric care benefits, such as softness, wrinkle reduction, and shape retention, while maintaining stability and compatibility with enzymes and surfactants.

Implementation Method 1

deposition aids (for example, cationic deposition polymers) suitable for enhancing the deposition of fabric care benefit agents

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Data Source

PatentUS8263544B2Detergent compositions for cleaning and fabric care
Publication Date: 2012.09.11 PROCTER & GAMBLE CO
  • US8263544B2 patent drawing
  • US8263544B2 patent drawing
  • US8263544B2 patent drawing

AI summary

Detergent compositions comprising selected deposition polymers for improved deposition of fabric care benefit agents, such as organosilicones, polyolefin dispersions, polymer latexes, microencapsulated fabric care actives, onto fabrics through the laundering operation.