Cationic Electrodeposition Emulsion Preparation Without Desolvation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The existing methods for preparing cationic electrodeposition paint compositions require the use of organic solvents like MIBK and xylene to reduce viscosity and improve handleability, which burdens the environment and increases production costs due to the need for a desolvation step, and these methods do not effectively reduce production time or eliminate the desolvation step.

Innovation Solution

A method involving the formation of a W/O emulsion with a cationic resin and a blocked isocyanate curing agent, followed by phase inversion to an O/W emulsion, where the blocked isocyanate curing agent is added after forming the W/O emulsion, reducing the need for MIBK and xylene and allowing for stable emulsion formation at elevated temperatures without adverse effects on handleability or film smoothness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If organic solvent (MIBK and xylene) is added to reduce viscosity of resin component, then handleability in mixing and transferring is improved, but environmental load increases and desolvation step is required

Engineering Contradiction:
ImprovehandleabilityVSAvoidenvironmental load
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent changes the temperature parameter during emulsion preparation (elevated temperature of 50-100°C) to reduce resin viscosity and improve handleability without adding organic solvents. This temperature parameter change allows the resin to be processed at lower solid contents while avoiding the need for MIBK and xylene, thus resolving the contradiction between ease of operation and environmental load.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces expensive and environmentally harmful organic solvents (MIBK and xylene) with a temporary elevated temperature condition that serves the same viscosity-reduction purpose but leaves no harmful residue requiring desolvation, effectively substituting a harmful substance with a temporary process parameter change.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If organic solvent is removed in desolvation step, then environmental load is reduced, but production time increases and production cost increases

Engineering Contradiction:
Improveenvironmental loadVSAvoidproduction time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent extracts the harmful desolvation step entirely from the process by preventing organic solvent addition in the first place. By formulating the emulsion at elevated temperature without MIBK and xylene, the patent eliminates the need for subsequent solvent removal, thus removing the time-consuming and costly desolvation step while maintaining environmental benefits.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs preliminary viscosity reduction through temperature control during the emulsion formation stage itself, rather than relying on organic solvents that would require later removal. This preliminary action at the correct temperature stage achieves the desired handleability without creating a subsequent desolvation requirement, saving both time and cost.

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If mixing operation is conducted at elevated temperature of 100°C or more to reduce viscosity, then handleability is improved, but epoxy resin and curing agent react and viscosity increases adversely

Engineering Contradiction:
ImprovehandleabilityVSAvoidviscosity stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent applies partial heating (50-100°C) rather than excessive high-temperature mixing, which is sufficient to reduce viscosity for handling but remains below the threshold that triggers significant epoxy-curing agent reaction. This partial action achieves the desired viscosity reduction while preventing the adverse viscosity increase from premature curing.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The patent performs the viscosity-reducing heating action preliminarily during emulsion formation, before the curing reaction significantly progresses. By establishing the correct temperature and viscosity conditions early in the process, the patent prevents subsequent viscosity increases from adverse reactions while maintaining stable composition throughout production.

Inventive Principle:
Principle #10Preliminary action

4Object-affected harmful factors

If solid content of curing agent-containing W/O emulsion is increased to reduce organic solvent, then environmental load is reduced, but phase inversion point is affected and emulsion stability may deteriorate

Engineering Contradiction:
Improveenvironmental loadVSAvoidemulsion stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent optimizes the solid content parameter of the curing agent-containing W/O emulsion to a specific range (40-70%) that simultaneously achieves low organic solvent content (environmental benefit) and maintains proper phase inversion characteristics (stability benefit). This parameter optimization ensures that the emulsion can undergo complete phase inversion to O/W type while remaining stable, resolving the contradiction between environmental load and emulsion stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces environmental load and CO2 emissions by minimizing the use of organic solvents, eliminates or shortens the desolvation step, and maintains the stability and smoothness of the coating film, while also reducing production time and costs.

Implementation Method 1

a step of mixing water and the cationic resin to form a W/O emulsion

Methodology Applied
Scientific EffectEmulsification: Emulsion

Implementation Method 2

a step of mixing the blocked isocyanate curing agent and the W/O emulsion to form a curing agent-containing W/O emulsion

Methodology Applied
Scientific EffectMixing: Stirring

Implementation Method 3

a step of mixing water and the curing agent-containing W/O emulsion to form an O/W emulsion, via a phase inversion point from W/O emulsion to O/W emulsion

Methodology Applied
Scientific EffectPhase inversion: Phase Change

Data Source

PatentEP2752467B1Method for preparing emulsion resin composition for cationic electrodeposition coating
Publication Date: 2016.07.13 NIPPON PAINT AUTOMOTIVE COATINGS
  • EP2752467B1 patent drawingFigure 1~2
  • EP2752467B1 patent drawingFigure 3
  • EP2752467B1 patent drawing

AI summary

The present invention is to provide a method for preparing an emulsion resin composition for a cationic electrodeposition paint, which prepare a cationic electrodeposition paint composition as reducing time for desolvation time or eliminating desolvation step. The present invention provide a method for preparing an emulsion resin composition for cationic electrodeposition paint, which comprises a cationic resin and a blocked isocyanate curing agent, the method comprises the steps: (1) a step of mixing water and the cationic resin to form a W/O emulsion, (2) a step of mixing the blocked isocyanate curing agent and the W/O emulsion to form a curing agent-containing W/O emulsion, (3) a step of mixing water and the curing agent-containing W/O emulsion to form an O/W emulsion, via a phase inversion point from W/O emulsion to O/W emulsion, wherein the cationic resin comprises a cationic epoxy resin, and a solid concentration by mass XW/O (%) of the curing agent-containing W/O emulsion and a solid content by mass Xtra (%) at the phase inversion point from W/O emulsion to O/W emulsion satisfy a relation of XW/O - Xtra > 3%.