Cationic Microfibrillated Plant Fiber for Uniform Nanofibrillation

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Solution Overview

Problem

Existing methods for producing microfibrillated plant fibers result in varying levels of fiber dispersibility and surface damage, leading to inconsistent properties in sheets and resin composites, such as strength, due to differences in defibration and chemical treatment methods.

Innovation Solution

A method involving cationic modification of cellulose fibers using a quaternary-ammonium-group-containing cationization agent followed by mechanical defibration in water to produce microfibrillated plant fibers with enhanced strength and uniformity, achieving an average diameter of 4 to 200 nm.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If mechanical defibration or chemical treatment is applied to enhance nanofibrillation, then fiber refinement is improved, but fiber dispersibility and surface quality vary leading to inconsistent strength properties

Engineering Contradiction:
Improvefiber refinement uniformityVSAvoidsheet and resin composite strength
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent applies cationic modification to the cellulose fibers before defibration treatment. This preliminary chemical treatment introduces positive charges on the fiber surface, which prevents fiber aggregation during subsequent mechanical processing and ensures uniform dispersibility. The cationic groups are grafted onto the fiber surface in advance, creating a stable foundation for achieving consistent nanofibrillation and uniform fiber properties in the final product, thereby resolving the contradiction between refinement uniformity and strength consistency.

Inventive Principle:
Principle #10Preliminary action

2Strength

If cationic modification is applied to enhance fiber bonding through electrostatic interaction, then strength is improved, but fiber dispersibility may be affected

Engineering Contradiction:
Improvefiber bonding strengthVSAvoidfiber dispersibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent carefully controls the degree of cationic substitution and the density of cationic groups on the fiber surface. By optimizing these parameters, the invention achieves a balance where sufficient cationic charges are present to provide strong electrostatic bonding between fibers (improving strength), while the modification does not create excessive fiber aggregation that would hinder dispersibility. The controlled parameter adjustment ensures both improved fiber bonding and maintained ease of handling.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If extensive chemical treatment is applied to improve water retentivity, then water retentivity is enhanced, but fiber surface damage and property inconsistency increase

Engineering Contradiction:
Improvewater retentivityVSAvoidfiber surface quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent employs cationic modification with controlled degree of substitution to improve water retentivity. The cationic groups introduced through this treatment enhance the fiber's ability to retain water by creating hydrophilic sites on the fiber surface. By carefully controlling the modification parameters (amount of cationic agent, reaction conditions), the invention achieves improved water retentivity while minimizing excessive surface damage and maintaining fiber property consistency, avoiding the pitfalls of extensive chemical treatment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of microfibrillated plant fibers with significantly high strength, suitable for a wide range of applications including interior materials, structural components, and electronic devices, by enhancing fiber bonding through electrostatic interactions and improving mechanical properties.

Implementation Method 1

reacting hydroxyl groups in a material containing a cellulose fiber with a quaternary-ammonium-group-containing cationization agent to cationically modify the material containing a cellulose fiber

Methodology Applied
Scientific EffectCationic modification: Chemical Bonding

Implementation Method 2

bonding between fibers is enhanced by electrostatic interaction

Methodology Applied
Scientific EffectElectrostatic interaction: Electrostatics

Implementation Method 3

microfibrillation can significantly proceed by applying mechanical shear stress to a plant fiber that has been cationically modified

Methodology Applied
Scientific EffectMechanical shear stress: Shear Stress

Data Source

PatentUS8969441B2Cationic microfibrillated plant fibre and manufacturing method for same
Publication Date: 2015.03.03 NIPPON PAPER IND CO LTD
  • US8969441B2 patent drawing
  • US8969441B2 patent drawing
  • US8969441B2 patent drawing

AI summary

The present invention provides a novel cationized microfibrillated plant fiber and a method for manufacturing the same. A cationic microfibrillated plant fiber that is cationically modified with a quaternary-ammonium-group-containing compound, and that has an average diameter of 4 to 200 nm.