Cationic Gel Particle for Intracellular Delivery

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Solution Overview

Problem

Current methods face challenges in delivering components or compounds into cells without inhibiting cell proliferation or differentiation, particularly in selecting polymers that can easily enter cells without disrupting cellular processes.

Innovation Solution

Development of a novel intracellular delivery vehicle, specifically a cationic gel particle with a positive charge, synthesized through radical polymerization using a cationic polymerization initiator and monomers, which allows easy introduction into cells without affecting cell survival, proliferation, or differentiation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If cationic polymers are used for intracellular delivery, then delivery efficiency is improved, but cell proliferation is inhibited

Engineering Contradiction:
Improvedelivery efficiencyVSAvoidcell proliferation
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the chemical structure of cationic polymers by introducing specific side chains (e.g., polyethylene glycol chains, carboxylic acid groups) to adjust the balance between positive charge density and biocompatibility. This parameter change allows the polymer to maintain sufficient cationic character for efficient cellular uptake while reducing toxicity to cell proliferation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite polymer structures combining cationic moieties with biocompatible segments (such as PEG chains and hydrophilic side groups). This composite approach enables the delivery vehicle to exhibit both high delivery efficiency through cationic interactions and reduced cytotoxicity through the biocompatible components

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If cationic polymers are introduced into cells, then intracellular delivery is achieved, but cell division is inhibited

Engineering Contradiction:
Improveintracellular deliveryVSAvoidcell division inhibition
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by concentrating the cationic charge primarily at the polymer's terminal groups or side chains rather than throughout the entire backbone. This localized cationic distribution enables effective interaction with cellular membranes for delivery while minimizing disruption to intracellular processes that would inhibit cell division

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional polymerization methods are used, then polymer production is achieved, but selective polymer identification for cell-compatible delivery is difficult

Engineering Contradiction:
Improvepolymer productionVSAvoidpolymer selection for cell-compatible delivery
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The patent establishes specific parameter ranges for polymer structure (charge density, molecular weight, side chain length and composition) that correlate with cell compatibility. These defined parameters provide clear selection criteria for identifying polymers suitable for intracellular delivery without inhibiting cellular functions

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The vehicle enables efficient delivery of desired components into cells with minimal impact on cellular functions, as demonstrated by its ability to introduce temperature-sensitive probes without inhibiting cell division or differentiation, showcasing its biocompatibility and effectiveness.

Implementation Method 1

synthesized through radical polymerization using a cationic polymerization initiator and monomers

Methodology Applied
Scientific EffectRadical polymerization: Photopolymerisation

Implementation Method 2

an arbitrarily shaped gel particle of which surface is covered with a positive charge

Methodology Applied
Scientific EffectElectrostatic interaction: Electrostatics

Data Source

PatentEP3760193B9Intracellular delivery vehicle
Publication Date: 2023.11.01 KIRIN HOLDINGS KK
  • EP3760193B9 patent drawingFigure 1
  • EP3760193B9 patent drawingFigure 2
  • EP3760193B9 patent drawingFigure 3

AI summary

An intracellular delivery vehicle of which surface is covered by a positive charge, an intracellular delivery complex in which a component or compound desired is loaded in the intracellular delivery vehicle, a temperature-sensitive probe comprising the intracellular delivery complex, and a method for measuring the intracellular temperature by the temperature-sensitive probe are disclosed. The intracellular delivery vehicle is useful on account of its capability of easily delivering the component or compound desired inside the cell without inhibiting cell proliferation.