Cationic Polymer Suds Control in Laundry Detergents

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Solution Overview

Problem

Current laundry detergents face challenges in achieving a strong sudsing profile during wash cycles while minimizing suds retention and eliminating suds quickly during rinse cycles, which is essential for environmental sustainability and consumer perception, without compromising cleaning performance or causing fabric whiteness loss.

Innovation Solution

A cationic polymer copolymer composed of (meth)acrylamide, diallyl dimethyl ammonium salt, and optional vinylpyrrolidone units, with specific molecular weight and monomeric ratios, is incorporated into a laundry detergent composition to optimize sudsing profile and reduce fabric whiteness loss, ensuring high Wash Suds Index and low Rinse Suds Index.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If conventional polymeric de-foaming or anti-foaming agents are added to reduce suds during rinse cycles, then suds elimination is improved, but fabric whiteness loss increases

Engineering Contradiction:
Improvesuds retentionVSAvoidfabric whiteness loss
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by carefully controlling the molecular weight of the cationic polymer within a specific range (5,000 to 500,000 Daltons) and adjusting the molar percentages of monomeric units (5-50% diallyl dimethyl ammonium salt, 50-95% (meth)acrylamide). These parameter optimizations enable the polymer to achieve effective suds elimination while minimizing fabric whiteness loss, resolving the technical contradiction between foam control and fabric care.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material approach by creating a copolymer that combines two distinct monomeric units: diallyl dimethyl ammonium salt (which provides cationic charge for suds control) and (meth)acrylamide (which provides backbone structure and fabric compatibility). This composite polymer structure integrates the beneficial properties of both monomers to simultaneously achieve suds elimination and fabric protection.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If de-foaming agents are added during rinse cycles to eliminate suds, then suds control is improved, but cleaning performance perception deteriorates

Engineering Contradiction:
Improvesuds volume during rinseVSAvoidconsumer perception of cleaning performance
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent applies segmentation by dividing the detergent formulation into functional components with distinct roles: the cationic polymer specifically targets suds elimination during rinsing, while anionic surfactants maintain cleaning performance during washing. This functional segmentation allows suds control without compromising the perceived cleaning effectiveness, as each component operates in its optimized phase.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs dynamics by enabling the cationic polymer to dynamically interact with and destabilize suds structures during the rinse cycle. The polymer's cationic charges actively bind to anionic surfactant molecules in the suds, causing rapid collapse and elimination of foam. This dynamic action provides visible suds reduction that signals effective rinsing to consumers without implying poor cleaning performance.

Inventive Principle:
Principle #15Dynamics

3Object-generated harmful factors

If cationic polymer with high molecular weight is used to control suds, then suds elimination is improved, but fabric whiteness loss increases

Engineering Contradiction:
Improvesuds retentionVSAvoidfabric whiteness loss
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by establishing an optimized molecular weight range (5,000 to 500,000 Daltons) for the cationic polymer. This parameter optimization balances two competing requirements: sufficient molecular weight to provide effective suds elimination through adequate chain entanglement and viscosity, while limiting molecular weight to prevent excessive polymer-fabric interactions that cause whiteness loss. The specified range represents the optimal compromise point.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3122857B1Method of cleaning fabrics comprising compositions containing cationic polymers
Publication Date: 2019.09.04 PROCTER & GAMBLE CO
  • EP3122857B1 patent drawing
  • EP3122857B1 patent drawing
  • EP3122857B1 patent drawing

AI summary

A laundry detergent composition comprises a cationic polymer for sudsing profile optimization. The polymer comprises (i) from 60 mol% to 95 mol% of a first structural unit derived from (meth)acrylamide; (ii)from 5 mol% to 40 mol% of a second cationic structural unit; and (iii) from 0 mol% to 25 mol% of a third nonionic structural unit that is different from the first structural unit. The polymer is substantially free of any silicone-derived structural component.