Liquid Laundry Detergent with Cationic Polysaccharide and Cellulose

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Solution Overview

Problem

Liquid laundry detergent compositions containing linear alkylbenzene sulphonate anionic surfactants struggle to provide both effective cleaning and fabric softening benefits without compromising fabric whiteness.

Innovation Solution

A liquid laundry detergent composition comprising amine-neutralized C12-14 linear alkylbenzene sulphonate, a cationically modified polysaccharide, and a cellulosic polymer, which are combined in specific weight percentages to provide both fabric softening and improved whiteness benefits, and can be formulated into a water-soluble unit dose article for convenient use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If cationically modified polysaccharides are added to provide fabric softening benefits, then fabric softness is improved, but fabric whiteness is compromised

Engineering Contradiction:
Improvefabric softnessVSAvoidfabric whiteness
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent combines cationically modified polysaccharides (for softening) with cellulosic polymers (for whiteness maintenance) and amine-neutralized linear alkylbenzene sulphonate (for cleaning) into a composite detergent formulation. This composite approach allows the synergistic interaction of multiple materials to achieve both softening and whiteness benefits simultaneously, resolving the contradiction between fabric softness and whiteness maintenance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies precise concentration ranges for each component: cationically modified polysaccharides at 0.05-3%, cellulosic polymers at 0.05-3%, and amine-neutralized linear alkylbenzene sulphonate at 5-35%. By optimizing these parameter ranges, the formulation achieves the desired balance between fabric softening and whiteness maintenance, transforming the trade-off into a controlled composition space where both benefits coexist

Inventive Principle:
Principle #35Parameter changes

2Productivity

If linear alkylbenzene sulphonate is used for effective fabric cleaning, then cleaning performance is improved, but fabric softening benefit is reduced

Engineering Contradiction:
Improvefabric cleaning efficiencyVSAvoidfabric softness
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent merges the cleaning function of linear alkylbenzene sulphonate with the softening function of cationically modified polysaccharides and the whiteness maintenance function of cellulosic polymers into a single integrated detergent composition. This combination allows all three functions (cleaning, softening, and whiteness maintenance) to be achieved simultaneously in one product application

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The detergent composition is designed to perform multiple functions: linear alkylbenzene sulphonate provides cleaning, cationically modified polysaccharides provide softening, and cellulosic polymers provide whiteness maintenance. This multi-functional formulation eliminates the need for separate cleaning and softening treatments, achieving universal benefit in a single wash cycle

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively enhances fabric softness while maintaining whiteness, as demonstrated by tests showing improved fabric feel and no compromise in whiteness maintenance, even after multiple wash cycles.

Implementation Method 1

cationically modified polysaccharides may be added to the liquid laundry detergent composition

Methodology Applied
Scientific EffectElectrostatic attraction: Ion Repulsion/Attraction

Implementation Method 2

liquid laundry detergent compositions comprising linear alkylbenzene sulphonate anionic surfactant are known and used for cleaning fabrics

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentEP3293247B1A liquid laundry detergent composition comprising a first polymer and a second polymer
Publication Date: 2020.06.17 PROCTER & GAMBLE CO
  • EP3293247B1 patent drawing
  • EP3293247B1 patent drawing
  • EP3293247B1 patent drawing

AI summary

The present invention discloses liquid laundry detergent compositions comprising a first and second polymer