Cationic Starch Ware Washing Composition for Low-Foam Drying

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Solution Overview

Problem

Existing ware washing processes face challenges with cationic guar and cationic celluloses due to high foam levels, chemical and physical instability, and inferior drying performance, especially on plastic substrates, which limits their effectiveness and usability in mechanical ware washing.

Innovation Solution

The use of cationic starches, such as Hi-Cat CWS 42, in the ware washing detergent composition, which provides improved drying performance, reduced foam formation, and stability, even in the absence of nonionic surfactants, allowing for effective sheeting action during the rinse step without the need for separate rinse aids.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cationic guar or cationic cellulose is used in the main wash detergent, then drying performance on glass and metal substrates is improved, but foam level increases excessively and drying performance on plastic substrates remains insufficient

Engineering Contradiction:
Improvedrying performanceVSAvoidfoam level
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the polysaccharide by using cationic starch with specific degree of substitution (0.03-0.15) and molecular weight (50,000-500,000), which modifies the foam generation characteristics while maintaining drying effectiveness across different substrate types including plastics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent combines cationic starch with nonionic surfactants in specific weight ratios (1/1 to 10/1 of polysaccharide to surfactant) to create a composite detergent system that achieves both low foam levels and excellent drying performance on various substrates

Inventive Principle:
Principle #40Composite materials

2Reliability

If high levels of nonionic surfactant are combined with cationic starch, then cleaning performance is enhanced, but chemical instability occurs with chlorine and physical instability arises in liquid compositions

Engineering Contradiction:
Improvecleaning performanceVSAvoidchemical and physical stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent optimizes the concentration parameters of nonionic surfactant to specific ranges (0.01-1% by weight) and controls the weight ratio between polysaccharide and surfactant (1/1 to 10/1), which prevents chemical instability with chlorine while maintaining cleaning effectiveness and physical stability in liquid compositions

Inventive Principle:
Principle #35Parameter changes

3Reliability

If cationic cellulose is used to improve drying performance, then sheeting action is achieved, but substantial foaming occurs and mechanical washing action is reduced

Engineering Contradiction:
Improvesheeting actionVSAvoidfoam interference with mechanical action
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the polysaccharide type from cationic cellulose to cationic starch with specific molecular weight and degree of substitution, which provides effective sheeting action for water removal while generating minimal foam that does not interfere with mechanical washing action

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Cationic starches enhance drying behavior on various substrates, including plastics, with improved drying coefficients and reduced residual droplets, while maintaining non-foaming properties and stability, offering a simpler and cost-effective ware washing process.

Implementation Method 1

polysaccharides adsorbing on the ware in the main wash process result in a sheeting action and good drying properties

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2364350B1Ware washing system containing cationic starch
Publication Date: 2019.09.18 DIVERSEY INC
  • EP2364350B1 patent drawing
  • EP2364350B1 patent drawing
  • EP2364350B1 patent drawing

AI summary

The present invention discloses a method of washing ware, in particular in an automatic domestic or institutional ware washing machine, using a detergent composition containing a cationic starch. This eliminates the need for a surfactant in the rinse step. The cationic starch provides a layer of cationic starch on the ware so as to afford a sheeting action in an aqueous rinse step without any added rinse agent.