Catmint Oil Recovery via Solvent Extraction

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Solution Overview

Problem

Current methods for recovering catmint oil from Nepeta plants result in low yields due to the oil's similar density to water and nepetalactone's hydration at high temperatures, leading to unwanted side products and inefficient separation in steam distillation processes.

Innovation Solution

The method involves steam distillation of Nepeta plant material to form a volatilized mixture, followed by condensation and separation, with the addition of a non-water miscible organic solvent to enhance the separation of catmint oil from water, allowing for the isolation of catmint oil through solvent extraction and removal under reduced pressure, thereby increasing yield.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If steam distillation is used to extract catmint oil, then the oil can be obtained from Nepeta plant material, but the yield is low due to similar density between oil and water and nepetalactone hydration at high temperatures

Engineering Contradiction:
Improvecatmint oil yieldVSAvoidnepetalactone loss due to hydration
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The patent changes the temperature parameter by conducting extraction at moderate temperatures (below the hydration threshold of nepetalactone) rather than high temperatures, thereby preventing unwanted side reactions and improving yield

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a non-water-miscible organic solvent as an intermediary substance to facilitate the separation of catmint oil from water. This solvent acts as a mediator that selectively extracts the oil phase, overcoming the density similarity problem between oil and water

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If standard steam distillation separation is used, then the process is simple, but separation efficiency is poor due to similar density between catmint oil and water

Engineering Contradiction:
Improveseparation efficiencyVSAvoidextraction process complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

A non-water-miscible organic solvent is introduced as an intermediary to enhance separation. This solvent selectively dissolves catmint oil from the aqueous phase, creating distinct layers that are easier to separate, thereby improving productivity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies local quality by using a solvent with specific properties (non-water-miscible, appropriate density difference) targeted at the oil-water interface, improving separation efficiency in the critical separation zone without complicating the entire system

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances catmint oil recovery by up to 50% or more, achieving overall yields of 80% or greater, overcoming the limitations of standard steam distillation techniques by effectively separating and isolating catmint oil at moderate temperatures.

Implementation Method 1

contacting Nepeta plant material with steam to form a volatilized mixture comprising catmint oil and water

Methodology Applied
Scientific EffectSteam distillation: Distillation

Implementation Method 2

condensing the volatilized mixture to form a first liquid mixture comprising catmint oil and water

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

contacting the first liquid mixture with at least one non-water miscible organic extracting solvent to form a second liquid mixture that contains a solvent phase and an aqueous phase

Methodology Applied
Scientific EffectLiquid-liquid extraction: Liquid-Liquid Extraction

Implementation Method 4

removing the extracting solvent from the solvent phase to isolate the catmint oil

Methodology Applied
Scientific EffectEvaporation under reduced pressure: Evaporation

Data Source

PatentUS9085747B2Method for the enhanced recovery of catmint oil
Publication Date: 2015.07.21 DUPONT US HOLDING LLC

AI summary

A high yielding method is described for recovery of catmint oil from catmint plants of the genus Nepeta by improved separation of a catmint oil containing phase from the condensed steam distillate of catmint plants. Catmint oil may be obtained in quantitative yields for use in insect repellent compositions.