Caustic Composition with Amino Acid Buffering

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Solution Overview

Problem

Conventional caustic compositions used in the oil and gas industry are hazardous, highly corrosive, and pose environmental risks due to their high toxicity, reactivity with metals, and inability to biodegrade, leading to significant operational and environmental challenges, including equipment damage, human safety concerns, and costly cleanup procedures.

Innovation Solution

A novel caustic composition comprising a caustic component, such as potassium hydroxide or sodium hydroxide, combined with an amino acid additive that provides an extended, linear buffering effect and lowers the freeze point, along with water, to enhance dermal protection and improve handling safety while maintaining pH control and impurity removal capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional caustic compositions (sodium hydroxide, potassium hydroxide) are used for pH control and impurity removal, then effective chemical function is achieved, but high toxicity and dermal damage risks increase

Engineering Contradiction:
ImprovepH control effectivenessVSAvoiddermal damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces amino acid additives (such as lysine, arginine, or histidine) as intermediary substances that buffer the caustic composition. These amino acids act as mediators between the strong base and the environment (skin, equipment), reducing the harmful effects while maintaining the pH control function. The amino acids provide buffering capacity that limits extreme pH changes, thereby protecting against dermal damage while preserving the effectiveness of impurity removal.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite caustic composition by combining conventional strong bases (sodium hydroxide or potassium hydroxide) with amino acid additives. This composite formulation integrates the pH control effectiveness of the strong base with the protective buffering properties of the amino acids, achieving both functional performance and reduced toxicity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If high concentration caustic solutions (50% sodium hydroxide) are used for bitumen extraction, then extraction efficiency is improved, but freeze point increases causing operational issues

Engineering Contradiction:
Improvebitumen extraction efficiencyVSAvoidfreeze point
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

The patent modifies the chemical composition parameters of the caustic solution by adding amino acid additives. This compositional change affects the physical properties of the solution, specifically lowering the freeze point while maintaining the high concentration needed for effective bitumen extraction. The amino acids alter the solution's colligative properties, enabling it to remain liquid at lower temperatures.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional caustic compositions are used for pH control, then alkalinity control is achieved, but buffering effect is limited and pH control is not extended

Engineering Contradiction:
Improvealkalinity controlVSAvoidbuffering duration
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The amino acid additives provide continuous buffering action that extends the duration of effective pH control. The amino acids gradually release and absorb protons, maintaining stable pH levels over an extended period. This continuous buffering action ensures sustained alkalinity control throughout the operational cycle, preventing rapid pH fluctuations.

Inventive Principle:
Principle #20Continuity of useful action

4Reliability

If conventional caustic compositions are used, then impurity removal capability is maintained, but environmental harm and lack of biodegradability increase

Engineering Contradiction:
Improveimpurity removal capabilityVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The amino acid additives are biodegradable substances that can be naturally broken down and recovered by environmental systems. After performing their buffering function, the amino acids can be metabolized by microorganisms, converting them into harmless byproducts. This allows the system to discard the additives safely into the environment without causing long-term harm, unlike conventional caustic compositions that persist and accumulate.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel composition offers improved safety and environmental responsibility by reducing dermal damage, lowering the freeze point, and providing precise pH control, thus minimizing operational risks and environmental impact while maintaining the effectiveness of caustic functions in oil and gas operations.

Implementation Method 1

an additive adapted to provide an extended (more methodical and linear) buffering effect to the caustic composition as well as greatly lowering the freeze point

Methodology Applied
Scientific EffectBuffering effect:

Implementation Method 2

an additive adapted to provide an extended (more methodical and linear) buffering effect to the caustic composition as well as greatly lowering the freeze point

Methodology Applied
Scientific EffectFreeze point depression:

Data Source

PatentUS11407647B2Synthetic caustic composition
Publication Date: 2022.08.09 DORF KETAL CHEM FZE
  • US11407647B2 patent drawing
  • US11407647B2 patent drawing
  • US11407647B2 patent drawing

AI summary

An aqueous caustic composition comprising: a caustic component; an amino acid additive adapted to provide an extended buffering effect to the caustic composition when such is exposed to an acid; and water, wherein the caustic component and the amino acid additive are present in a molar ratio ranging from 15:1 to 5:1. Methods of using such compositions are also disclosed.