Phosphate-Free Caustic Detergent with Chelating Acid Rinse

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Solution Overview

Problem

Conventional cast warewashing detergents containing carbonates exacerbate hard water scaling, and phosphorus-based builders face environmental and health concerns, necessitating a more effective and environmentally friendly cleaning system.

Innovation Solution

A detergent system comprising a caustic detergent and an acidic rinse solution, where the detergent is primarily alkali metal hydroxide-based and free of alkali metal carbonates and phosphorus, paired with a chelating acid in the rinse solution to prevent water hardness precipitation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If carbonates are included in detergents to provide alkalinity and buffer capacity, then the detergent maintains stable pH and cleaning effectiveness, but hard water scaling is exacerbated

Engineering Contradiction:
ImprovepH stability and cleaning effectivenessVSAvoidhard water scaling
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention removes carbonates from the detergent formulation entirely, extracting the problematic component that causes scaling while maintaining cleaning effectiveness through alternative ingredients such as caustic and chelating agents

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters by substituting carbonates with caustic-based systems combined with chelating agents, fundamentally altering how alkalinity and water hardness are managed in the cleaning system

Inventive Principle:
Principle #35Parameter changes

2Productivity

If phosphorus-containing materials are used to reduce water hardness and increase detergency, then cleaning performance and soil suspension are improved, but environmental and health concerns arise leading to regulatory restrictions

Engineering Contradiction:
Improvedetergency and soil suspensionVSAvoidenvironmental and health impact
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The invention completely eliminates phosphorus-containing materials from the detergent formulation, removing the environmentally harmful component while maintaining cleaning performance through phosphate-free alternatives

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses biodegradable, environmentally safe ingredients that break down harmlessly, replacing persistent phosphorus compounds with short-lived, non-toxic alternatives that do not accumulate in the environment

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If a caustic-based detergent system is used to effectively remove soils, then cleaning effectiveness is improved, but corrosion of surfaces may occur

Engineering Contradiction:
Improvesoil removal effectivenessVSAvoidsurface corrosion
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention introduces corrosion inhibitors as intermediary substances that mediate between the caustic detergent and metal surfaces, protecting the surfaces from direct contact with corrosive agents while allowing the caustic to perform its cleaning function

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention removes the corrosive effect by separating the cleaning function (caustic) from the harmful effect (corrosion), using additional ingredients to neutralize or block the harmful interaction

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively removes soils, prevents redeposition, and reduces scaling on surfaces, offering a green and biodegradable alternative for various cleaning applications while minimizing environmental impact.

Implementation Method 1

The rinse solution includes water and a chelating acid

Methodology Applied
Scientific EffectChelation:

Implementation Method 2

the detergent composition is also substantially free of alkali metal carbonates

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS8802611B2Highly concentrated caustic block for ware washing
Publication Date: 2014.08.12 ECOLAB USA INC

AI summary

A system for cleaning ware includes a detergent composition and a rinse solution. The detergent composition includes an alkali metal hydroxide, a corrosion inhibitor and a surfactant. The detergent includes less than about 1% of an alkali metal carbonate by weight. The rinse solution includes water and a chelating acid.