Cavitation Fuel Purification for Zero Sulfur Dioxide Emissions

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Solution Overview

Problem

Existing methods for purifying oil and oil products from sulfur-containing compounds are complex and generate waste, while current methods for reducing sulfur content in diesel fuel only and do not effectively address sulfur dioxide emissions in exhaust gases during combustion.

Innovation Solution

The method involves treating liquid hydrocarbon motor fuels with hydrogen peroxide and/or a strong aqueous solution of iron oxides in a fully-developed cavitation mode, followed by separation using polymer membranes to achieve a sulfur content of 20 ppm or less, and further reducing sulfur dioxide emissions to zero during combustion without additional chemical substances.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If existing methods for purifying oil from sulfur compounds are used, then sulfur content is reduced, but the process complexity increases and waste is generated

Engineering Contradiction:
Improvesulfur content reductionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention extracts sulfur-containing compounds from fuel by adding extraction agents (acidic or basic substances) that selectively bind to sulfur compounds, forming separable complexes. This allows sulfur removal without complex multi-step processes, directly addressing the contradiction between purification effectiveness and process simplicity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical parameters of the fuel by introducing extraction agents that alter the solubility and separability of sulfur compounds. By adjusting parameters such as pH through acidic or basic additives, the method enables efficient sulfur removal while maintaining process simplicity

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If existing methods for purifying diesel fuel from sulfur compounds are used, then sulfur-containing compounds content is reduced, but waste is formed that must be disinfected or stacked

Engineering Contradiction:
Improvesulfur-containing compounds content reductionVSAvoidwaste formation
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The invention enables recovery and reuse of the extraction agents (acidic or basic substances) after they have bound sulfur compounds. The spent extraction agent-sulfur complex can be regenerated and reused, minimizing waste disposal requirements and addressing the environmental concern of waste generation

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The invention converts the harmful sulfur compounds into separable complexes with extraction agents, transforming a harmful substance into a manageable form that can be easily removed and disposed of or regenerated, thereby converting a waste problem into a solvable separation problem

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-affected harmful factors

If sulfur content in fuel is reduced to 20 ppm or less, then emission standards are met, but additional processing steps are required

Engineering Contradiction:
Improveemission standards complianceVSAvoidprocessing efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The invention performs preliminary treatment of fuel with extraction agents before combustion, pre-removing sulfur compounds in advance. This preliminary action ensures that the fuel meets emission standards (20 ppm or less) without requiring complex post-processing or multiple treatment stages, thereby maintaining processing efficiency

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves a sulfur content reduction in fuels to 20 ppm or less and eliminates sulfur dioxide emissions in exhaust gases, enhancing fuel combustion efficiency and reducing harmful emissions.

Implementation Method 1

treating the fuel or a fuel fraction in the fully-developed cavitation mode with addition of a hydrogen peroxide aqueous solution and/or a strong aqueous solution of iron oxides

Methodology Applied
Scientific EffectCavitation: Cavitation

Implementation Method 2

treating the fuel or a fuel fraction in the fully-developed cavitation mode with addition of a hydrogen peroxide aqueous solution and/or a strong aqueous solution of iron oxides

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

separating the sulfur-containing modified molecules from the remainder of the fuel molecules on the polymer membranes

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 4

activating the fuel purified up to 20 ppm in the fully-developed cavitation mode prior to the combustion

Methodology Applied
Scientific EffectCavitation: Cavitation

Implementation Method 5

reduction of the sulfur dioxide content in exhaust gases up to zero during combustion of the fuels

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS11319497B2Method for purifying liquid hydrocarbon motor fuels from sulfur and for further reducing the sulfur dioxide content in exhaust gases up to zero during combustion of the fuels
Publication Date: 2022.05.03 UNIQUE EQUIPMENT SOLUTIONS LLC

AI summary

The invention relates to the oil-refining industry, in particular, to methods for purifying a fuel from sulfur-containing compounds, by separating the sulfur-containing modified molecules from the remainder of the fuel molecules on polymer membranes and by activating the fuel purified in the fully-developed cavitation mode prior to the combustion. The reduction of the sulfur content in the fuel is achieved by treating the fuel or a fuel fraction in the fully-developed cavitation mode with addition of a hydrogen peroxide aqueous solution and/or a strong aqueous solution of iron oxides, followed by separating the obtained emulsion into a fuel fraction and a water-paraffin emulsion, followed by separating the fuel fraction on the membranes under the temperature of from 90° C. to 180° C. under atmospheric pressure into a fuel fraction having low sulfur combustion of the purified fuels down to zero by means of activation of the fuels having the low sulfur content.