Cavity Ring Down System for Trace Gas Detection

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Solution Overview

Problem

Current methods for measuring atmospheric nitrogen dioxide (NO2) suffer from interferences, stability issues, and lack precision, leading to inaccurate readings.

Innovation Solution

A cavity ring down system is used to measure the presence of gases by collecting and analyzing currents during both the rise and fall times of light in an optical cavity, with multiple-sample averaging to achieve a high signal-to-noise ratio, allowing for precise detection of trace gases like NO2.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional methods are used to measure atmospheric NO2, then measurement capability is provided, but interference and lack of precision occur

Engineering Contradiction:
ImproveNO2 measurement precisionVSAvoidinterference
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The measurement process is segmented into distinct phases: light source ON期间收集电流(包括上升沿和稳态部分),光 Source OFF期间收集电流。通过时间分割,将信号采集分为多个阶段,使得可以分别处理不同阶段的信号,从而消除干扰并提高精度

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

在光 Source ON期间预先收集电流数据(包括上升沿电流和稳态电流),为后续计算做准备。通过预先收集多个周期的电流数据并进行积分处理,建立起准确的信号基线,从而在扣除背景后获得更精确的NO2浓度信息

Inventive Principle:
Principle #10Preliminary action

2Reliability

If conventional measurement methods are used, then gas detection is achieved, but stability is insufficient

Engineering Contradiction:
Improvemeasurement stabilityVSAvoiddetection accuracy
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

光 Source持续周期性地ON和OFF,在每个周期内连续收集电流数据。通过多个周期的连续测量和积分处理,累积有效信号的同时平均掉随机噪声,从而同时提高测量的稳定性和精度

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

通过比较光 Source ON期间的电流(包含背景信号)和OFF期间的电流(主要是背景信号),计算出由NO2吸收引起的净信号。这种反馈式的差分测量方法有效消除了背景漂移的影响,提高了测量稳定性

Inventive Principle:
Principle #23Feedback

3Measurement precision

If simple detection is used, then device complexity is reduced, but signal-to-noise ratio is insufficient

Engineering Contradiction:
Improvesignal-to-noise ratioVSAvoiddetection system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

光 Source采用周期性开关方式(ON-OFF-ON-OFF...),在每个周期内完成一次完整的测量循环。通过周期性激励和多个周期的积分处理,将微弱的NO2吸收信号从噪声中分离出来,显著提高信噪比

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

将光 Source ON期间的多个电流信号(上升沿电流+稳态电流)在时间域上叠加积分,将多个周期的测量结果累积处理。通过合并多个独立测量值,使信号线性叠加而噪声仅按平方根叠加,从而大幅提高信噪比

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides stable and precise measurements of NO2 by optimizing the cavity ring down system to account for both rise and fall times, enhancing sensitivity and reducing noise, thereby improving the accuracy of gas detection in air samples.

Implementation Method 1

measuring the at least one current resulting from light introduced into the optical cavity

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

A method of measuring the presence of a gas in an air sample using a cavity ring down system

Methodology Applied
Scientific EffectCavity ring down:

Implementation Method 3

collecting at least one current resulting from light introduced into an optical cavity

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentUS20130016353A1Electric gated integrator detection method & device thereof
Publication Date: 2013.01.17 GUNDERSEN JAMES LOWELL
  • US20130016353A1 patent drawing
  • US20130016353A1 patent drawing
  • US20130016353A1 patent drawing

AI summary

A cavity ring down system is optimized to precisely measure trace gases or particles in an air sample by using time sampling detection and multiple-sample averaging resulting in a high signal-to-noise ratio. In one embodiment, a cavity ring down system is programmed to measure the rise time and the fall time of the light level in an optical cavity. The cavity ring down system is programmed to integrate a plurality of sample portions during a rise time and a plurality of sample portions during a fall time (in alternate intervals) to obtain a time constant with no sample present and a time constant with sample present. The measurements are used to calculate trace gases in the air sample.