CCGT Flue Gas Recirculation With Electrolysis Oxygen for Smaller CCS

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Solution Overview

Problem

Existing combined cycle gas turbine systems face high investment and energy costs due to large carbon capture and storage units required for low CO2 content in flue gas, and renewable energy systems have intermittent production, complicating the reduction of these units' size and energy consumption.

Innovation Solution

An installation integrating a combined cycle gas turbine with a carbon capture and storage unit, a renewable electricity production unit, and an electrolysis unit, allowing for flexible operation modes and increased flue gas recirculation with pure oxygen addition, reducing the size and energy consumption of the carbon capture unit.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If a carbon capture and storage unit is used to capture CO2 from flue gas, then CO2 emissions are reduced, but the unit requires large size and huge investment costs due to low CO2 content in flue gas

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidsize and investment costs of CCS unit
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The flue gas flow is divided into two separate flows: a first gas flow sent to the CCS unit for CO2 capture, and a second gas flow recycled as working fluid. This segmentation allows the CCS unit to process only a portion of the flue gas, reducing its required size and investment costs while still achieving effective CO2 capture from the concentrated stream.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The CO2 concentration parameter in the gas stream is changed by selective routing. The first gas flow directed to the CCS unit has higher CO2 content than the original flue gas, which improves the efficiency and reduces the size of the capture unit. This parameter optimization allows the CCS unit to operate more effectively with smaller dimensions.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If flue gas is recirculated as part of the working fluid, then the amount of flue gas to be treated by the CCS unit is reduced, but the temperature of the working fluid increases and oxygen content decreases

Engineering Contradiction:
Improveamount of flue gas to be treatedVSAvoidtemperature of working fluid
Core Design Contradiction:
Quantity of substanceVSTemperature

Solution Approach 1:

The temperature parameter of the recirculated second gas flow is controlled and adjusted before mixing with the primary working fluid. By optimizing the temperature of the recirculated stream, the system reduces the amount of flue gas requiring CO2 capture while preventing excessive temperature increase in the combined working fluid that would compromise turbine performance.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If flue gas is recirculated as part of the working fluid, then the amount of flue gas to be treated by the CCS unit is reduced, but the oxygen content decreases reducing its ability to serve as an oxidizer

Engineering Contradiction:
Improveamount of flue gas to be treatedVSAvoidoxidizing ability of working fluid
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The oxygen concentration parameter in the recirculated second gas flow is managed by controlling the recirculation rate and mixing ratio. This ensures that while flue gas recirculation reduces the volume requiring CO2 capture, the oxygen content in the combined working fluid remains sufficient to maintain reliable combustion and oxidizing performance in the gas turbine.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The installation achieves CO2-free electricity production at reduced costs by minimizing the carbon capture unit's size and energy consumption, while utilizing renewable energy to stabilize power output.

Implementation Method 1

an electrolysis unit (32) adapted for receiving water and electrical energy and producing a hydrogen flow and an oxygen flow

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

a heat recovery steam generator, adapted for receiving the flow of first flue gas and producing steam

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

the working fluid is first compressed, then heated in the combustion chamber of the gas turbine where the fuel gas is burnt

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 4

the combustion products are expanded in the turbine part, thus producing mechanical power

Methodology Applied
Scientific EffectThermodynamic expansion: Heat Engine

Implementation Method 5

the steam turbine being adapted for receiving the steam and producing a second mechanical power

Methodology Applied
Scientific EffectThermodynamic expansion: Heat Engine

Data Source

PatentEP4558758B1Installation for producing electricity or mechanical power, comprising a combined cycle gas turbine, and co2 capture and water electrolysis units
Publication Date: 2026.03.04 TOTALENERGIES ONETECH
  • EP4558758B1 patent drawingFigure 1
  • EP4558758B1 patent drawingFigure 2

AI summary

An installation (10) for producing electricity (12) and/or mechanical power, comprising: - a CCGT unit (18), - a splitter (26) for receiving and splitting flue gas (68) into a first gas flow (92) and a second gas flow (94), - a CCS unit (28) for receiving the first gas flow and storing CO2, - a renewable electricity production unit (30), - an electrolysis unit (32) for producing an oxygen flow (102), - a mixing unit (34) for receiving the second gas flow and at least part of the oxygen flow, and for producing a working fluid (60) of a gas turbine (20). The installation is configured for switching between: - a first operation mode, in which the renewable electricity production unit produces renewable electricity (36), and the electrolysis unit uses at least some of it, - a second operation mode, in which the renewable electricity production unit is idle, and the electrolysis unit uses electricity (38) from the CCGT unit or a local grid (40).