Formaldehyde-Free Ceiling Tile Binder Resists Yellowing

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Solution Overview

Problem

There is a need for an environmentally friendly, no-added formaldehyde or formaldehyde-free binder composition for insulation products, particularly ceiling tiles, that resists yellowing and discoloration while maintaining stiffness and rigidity under humidity conditions.

Innovation Solution

A fibrous insulation product using a non-woven fiber mat bound by an aqueous binder composition comprising a thermally degradable polyol, a cross-linking agent, and an acid/aldehyde scavenger, which is free of added formaldehyde.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If no-added formaldehyde or formaldehyde-free binder composition is used, then environmental friendliness is improved, but yellowing and discoloration occur over time

Engineering Contradiction:
Improveformaldehyde emissionsVSAvoidcolor stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces an intermediary substance (ultraviolet absorber or hindered amine light stabilizer) that mediates between the binder composition and the harmful UV radiation. This intermediary absorbs or blocks UV light before it can cause photodegradation and yellowing of the binder, thereby maintaining color stability while using formaldehyde-free binders.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical composition parameters of the binder system by selecting specific polyol types (e.g., polyvinyl alcohol, polyvinyl acetate) and incorporating UV stabilizers. These parameter changes in the binder formulation improve resistance to yellowing while maintaining the formaldehyde-free characteristic.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If no-added formaldehyde or formaldehyde-free binder composition is used, then environmental friendliness is improved, but stiffness and rigidity under humidity conditions deteriorate

Engineering Contradiction:
Improveformaldehyde emissionsVSAvoidstiffness and rigidity under humidity
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent creates a composite binder system combining formaldehyde-free polyol resins with cross-linking agents and UV stabilizers. This composite formulation achieves both environmental friendliness (no formaldehyde) and improved performance (stiffness and rigidity under humidity) through synergistic interactions between the different components.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical and physical parameters of the binder composition, including selecting specific polyol types, adjusting molecular weight, and incorporating cross-linking agents. These parameter changes enable the binder to maintain stiffness and rigidity under humid conditions while remaining formaldehyde-free.

Inventive Principle:
Principle #35Parameter changes

3Strength

If traditional phenol-formaldehyde binder is used, then mechanical strength and stiffness are improved, but harmful emissions are generated

Engineering Contradiction:
Improvemechanical strength and stiffnessVSAvoidformaldehyde emissions
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes the harmful formaldehyde component from the binder system while retaining the beneficial mechanical properties. By using alternative formaldehyde-free polyol resins and cross-linking mechanisms, the invention eliminates formaldehyde emissions while maintaining or improving mechanical strength and stiffness.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters by replacing phenol-formaldehyde with alternative polyol-based binders. This parameter change in the binder chemistry eliminates harmful emissions while preserving the desired mechanical performance characteristics through careful selection of polyol types and cross-linking agents.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If NAF or formaldehyde-free binder is used, then environmental friendliness is improved, but uniform color cannot be maintained

Engineering Contradiction:
Improveformaldehyde emissionsVSAvoiduniform color
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces UV stabilizing intermediaries (ultraviolet absorbers or hindered amine light stabilizers) that protect the binder composition from UV-induced color variation. These intermediaries ensure uniform color across tiles from different boards by preventing differential yellowing during storage and service life.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces or eliminates yellowing and discoloration in ceiling tiles, maintains mechanical properties under hot/humid conditions, and provides a uniform color, addressing the challenges of formaldehyde-free binder compositions.

Implementation Method 1

an acid/aldehyde scavenger selected from the group consisting of alkali hydroxides; alkaline earth hydroxides; alkali carbonates and alkali bicarbonates; ammonium and/or alkali phosphates; mono-, di-, and poly-primary amines; secondary or tertiary amines; aromatic amines; amides and lactams; and sulfites

Methodology Applied
Scientific EffectAcid/base neutralization: Chemical Bonding

Implementation Method 2

a thermally degradable polyol

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 3

a cross-linking agent

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS20250116039A1Ceiling board and tile with reduced discoloration
Publication Date: 2025.04.10 OWENS CORNING INTELLECTUAL CAPITAL LLC
  • US20250116039A1 patent drawing
  • US20250116039A1 patent drawing
  • US20250116039A1 patent drawing

AI summary

A fibrous insulation product is provided comprising a nonwoven fiber mat including a plurality of fibers bound together by an aqueous binder composition comprising that includes a thermally degradable polyol; a crosslinking agent; and an acid/aldehyde. The binder composition is free of added formaldehyde.