Multilayer Cell Spacer Barrier for Thermal Runaway Gas Containment

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Solution Overview

Problem

Lithium-ion batteries are prone to thermal runaway due to abuse conditions, leading to catastrophic failures such as fires and explosions, and existing insulation materials fail to effectively mitigate heat propagation and gas containment, limiting energy density and safety.

Innovation Solution

A multilayer thermal barrier material comprising aerogel compositions, reinforced aerogel compositions, and sacrificial material layers with compressible pads, providing superior heat dissipation, fire resistance, and compressional resilience to accommodate cell expansion, while minimizing thickness and weight.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional insulation materials are used between battery cells, then thermal propagation is reduced to some extent, but the materials fail to effectively contain hot gases and ejecta from thermal runaway events

Engineering Contradiction:
Improvethermal propagationVSAvoidgas containment effectiveness
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent employs a composite material structure consisting of a porous core layer (for thermal insulation and gas absorption) surrounded by a dense skin layer (for gas containment and ejection protection). This composite structure simultaneously addresses thermal propagation reduction and hot gas containment, resolving the contradiction between thermal insulation and gas containment effectiveness.

Inventive Principle:
Principle #40Composite materials

2Temperature

If thicker insulation materials are used to improve thermal barrier performance, then heat dissipation is enhanced, but the device complexity and space requirements increase

Engineering Contradiction:
Improveheat dissipation performanceVSAvoidmaterial thickness and structure
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent applies different material properties to different regions of the thermal barrier: the core layer uses highly porous materials with low thermal conductivity for maximum insulation with minimal thickness, while the skin layer uses dense materials for gas containment. This localized differentiation of material quality achieves superior thermal barrier performance without requiring uniform thickness throughout, thereby reducing overall device complexity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes porous materials (such as aerogels, foam structures, or fibrous materials) in the core layer that provide exceptional thermal insulation with very low density and minimal thickness. The porous structure creates tortuous heat paths that significantly reduce thermal conductivity, enabling effective heat dissipation without increasing material thickness or device complexity.

Inventive Principle:
Principle #31Porous materials

3Object-affected harmful factors

If rigid insulation structures are used to prevent thermal runaway propagation, then thermal barrier performance is improved, but the structure cannot accommodate cell expansion during charging

Engineering Contradiction:
Improvethermal runaway protectionVSAvoidaccommodation of cell expansion
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent employs a dynamic structural design where the core porous layer can compress and deform elastically to accommodate battery cell expansion during charging cycles, while the dense skin layer maintains its structural integrity for thermal runaway protection. This dynamic adaptability allows the thermal barrier to adjust to changing cell dimensions without compromising its protective function.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent uses a flexible porous core structure that can deform and adapt to cell volume changes during charging and discharging. The porous network structure allows for compression and expansion while maintaining thermal insulation properties, providing both thermal runaway protection and adaptability to cell dimensional changes.

Inventive Principle:
Principle #30Flexible shells and thin films

4Reliability

If high-performance thermal barrier materials are used to enhance safety, then energy density is reduced due to increased material weight and volume

Engineering Contradiction:
Improvesafety performanceVSAvoidenergy density
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent utilizes highly porous insulation materials with extremely low density (such as aerogels or fine-cell foams) that provide superior thermal barrier performance per unit mass and volume. The porous structure contains大量 air pockets that inhibit heat transfer while adding minimal weight and occupying minimal space, thereby enhancing safety without significantly reducing energy density.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent segments the thermal barrier into two functional layers with distinct thicknesses and material properties: a thin dense skin layer for gas containment and a thicker porous core layer for thermal insulation. This segmentation optimizes the weight and volume distribution, ensuring that the majority of the material volume is dedicated to low-density insulation that provides maximum thermal protection per unit mass, thereby preserving energy density while enhancing safety.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer material effectively reduces thermal propagation and mitigates thermal runaway, enhancing safety and energy density by providing robust thermal management and containment of hot gases, thereby preventing damage to adjacent cells.

Implementation Method 1

at least one insulation layer, wherein the insulation layer has a thermal conductivity through a thickness dimension of the insulation layer of less than about 50 mW/m-K at 25° C.

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

at least one thermally conductive layer, wherein the thermally conductive layer has an in-plane thermal conductivity of at least about 200 mW/m-K

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 3

at least one thermally capacitive layer, wherein the thermally capacitive layer has a specific thermal capacity of at least about 200 J/(kg-K)

Methodology Applied
Scientific EffectThermal capacity: Heat Sink

Implementation Method 4

at least one compressible pad having a compression modulus of about 1 MPa to about 12 MPa

Methodology Applied
Scientific EffectCompression: Compression

Data Source

PatentUS12199260B2Devices, systems, and methods for controlling vent gases and ejecta from thermal runaway events in energy storage systems
Publication Date: 2025.01.14 ASPEN AEROGELS INC
  • US12199260B2 patent drawing
  • US12199260B2 patent drawing
  • US12199260B2 patent drawing

AI summary

The present disclosure relates to materials and systems to manage thermal runaway issues in battery modules. In exemplary embodiments, a battery module includes battery cells separated by spacer elements. To mitigate thermal runaway issues, spacer elements may be extended to the interior surface of the enclosure. A seal is formed between the spacer elements and the interior wall to form a thermal barrier between adjacent battery cells.