Cellular Geopolymer Product with Controlled Porosity

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Solution Overview

Problem

Cement-based materials in construction exhibit deformation, cracking, and high carbon footprints due to thermal and moisture effects, and energy-intensive production processes, necessitating a more stable and environmentally friendly alternative.

Innovation Solution

A method for manufacturing cellular geopolymer products by forming an activated geopolymer premix with an oxidized aluminum powder gas generating agent, controlling condensation reactions, and generating gas bubbles to create a self-supporting cellular structure with controlled viscosity and stiffness, offering structural and insulating properties comparable to conventional cement-based materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If cement-based materials are used in construction, then structural strength and durability are achieved, but dimensional stability deteriorates due to deformation, cracking, and drying shrinkage

Engineering Contradiction:
Improvestructural strengthVSAvoiddimensional stability
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent introduces a cellular (porous) structure into the geopolymer material by incorporating gas-generating agents during mixing. This porous structure reduces drying shrinkage by providing internal void space that accommodates volume changes, while maintaining structural strength through the geopolymer matrix that binds the cellular structure. The controlled porosity allows the material to achieve both strength and dimensional stability.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent creates a composite material system combining geopolymer binder with gas-generating agents (such as aluminum powder or chemical leavening agents). This composite approach allows the geopolymer matrix to provide structural strength while the gas-generated bubbles create a cellular structure that reduces drying shrinkage and improves dimensional stability.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If cement-based materials are used for construction, then building structures are achieved, but environmental impact increases due to high carbon footprint from energy-intensive production

Engineering Contradiction:
Improvemanufacturing capabilityVSAvoidcarbon footprint
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the binder system by replacing Portland cement with geopolymer binders (such as fly ash-based or slag-based geopolymers). This substitution maintains manufacturing capability while significantly reducing the carbon footprint, as geopolymers require lower curing temperatures and utilize industrial by-products, thereby converting waste materials into construction resources.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts industrial waste materials (fly ash, slag) into valuable geopolymer binders. These by-products, which would otherwise be environmental hazards requiring disposal, are transformed into functional construction materials through alkaline activation, thereby reducing carbon footprint while maintaining ease of manufacture.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Shape

If geopolymer premix is activated and gas bubbles are generated, then cellular structure is formed, but control of reaction kinetics and viscosity becomes critical to achieve self-supporting structure

Engineering Contradiction:
Improvecellular structureVSAvoidprocess control complexity
Core Design Contradiction:
ShapeVSDevice complexity

Solution Approach 1:

The patent incorporates gas-generating agents into the geopolymer premix before activation, so that gas bubble formation begins simultaneously with the geopolymerization reaction. This preliminary incorporation ensures that the cellular structure develops as the matrix stiffens, providing self-support before the material sets. The process controls complexity by synchronizing gas generation with viscosity increase, eliminating the need for separate aeration steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent maintains continuous gas generation throughout the geopolymerization process, ensuring that cellular structure formation occurs continuously as the matrix develops strength. This continuous action allows the material to support its own weight and maintain cellular morphology throughout curing, reducing process control complexity by avoiding discrete processing stages.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces cellular geopolymer products with enhanced mechanical strength, low drying shrinkage, and reduced environmental impact, providing a viable alternative to cement-based materials with improved durability and reduced carbon footprint.

Implementation Method 1

incorporating a gas generating agent in the activated geopolymer premix, wherein the gas generating agent is aluminum powder

Methodology Applied
Scientific EffectGas generation reaction: Chemical Bonding

Implementation Method 2

an activator compound that initiates a condensation reaction in the geopolymer premix

Methodology Applied
Scientific EffectCondensation reaction: Condensation

Data Source

PatentEP2760804B1Method for making a cellular geopolymer product
Publication Date: 2020.04.01 COMMONWEALTH SCI & IND RES ORG
  • EP2760804B1 patent drawingFigure 1

AI summary

A method for manufacturing a cellular geopolymer product, which method comprises the steps: (a) forming an activated geopolymer premix by addition to a geopolymer premix of an activator compound that initiates a condensation reaction in the geopolymer premix; (b) casting the activated geopolymer premix in a desired configuration; and (c) generating gas bubbles in the activated geopolymer premix as the condensation reaction proceeds and the activated geopolymer premix stiffens to produce a self-supporting cellular structure; and (d) curing the self-supporting cellular structure to produce the cellular geopolymer product, wherein in step (c) the characteristics of the activated geopolymer premix and the reaction kinetics of the condensation reaction are controlled to achieve formation of the self-supporting cellular structure.