Melt-Processable Cellulose Acetate via Fatty Acid Plasticization

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

There is a challenge in manufacturing single-use consumer products that are both biodegradable and have adequate performance and melt-processing properties, particularly due to the difficulties in using biodegradable materials like cellulose acetate in existing manufacturing systems without significant equipment changes, which can impact efficiency and material properties.

Innovation Solution

A melt-processable cellulose acetate composition comprising cellulose acetate, fatty acid, and an optional processing aid, which improves processability and article properties, allowing for the production of biodegradable and compostable products with enhanced performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If biodegradable materials like cellulose acetate are used in existing manufacturing systems, then environmental sustainability is improved, but equipment compatibility and processing efficiency deteriorate

Engineering Contradiction:
Improveenvironmental sustainabilityVSAvoidequipment compatibility
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent modifies processing parameters including temperature ranges, residence times, and shear rates to enable cellulose acetate to be processed in conventional equipment. The composition is heated to specific temperature ranges and processed under controlled conditions that prevent degradation while achieving proper flow and forming.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite composition by blending cellulose acetate with compatible polymers and additives. This composite approach improves melt flow properties, reduces viscosity, and enhances compatibility with existing manufacturing equipment while maintaining biodegradability.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If biodegradable materials like cellulose acetate are used in existing manufacturing systems, then environmental sustainability is improved, but material yields and processing efficiency deteriorate

Engineering Contradiction:
Improveenvironmental sustainabilityVSAvoidprocessing efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent optimizes processing parameters such as temperature, pressure, and residence time to maximize material yield. By controlling these parameters, the process minimizes material degradation and loss while maintaining high production rates and efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent enables continuous processing of cellulose acetate through conventional equipment by maintaining optimal processing conditions throughout the manufacturing cycle. This ensures uninterrupted production flow and maximizes productivity without sacrificing material yield.

Inventive Principle:
Principle #20Continuity of useful action

3Ease of manufacture

If cellulose acetate is heated to melt-processing temperatures, then processability is improved, but compositional components are lost and molecular weight decreases

Engineering Contradiction:
ImproveprocessabilityVSAvoidcompositional components loss
Core Design Contradiction:
Ease of manufactureVSLoss of substance

Solution Approach 1:

The patent employs controlled temperature ranges and reduced residence times during processing. By optimizing these parameters, the material achieves adequate melt flow and processability while minimizing thermal degradation, plasticizer loss, and molecular weight reduction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent incorporates stabilizers and protective additives in the composition formulation before processing. These preliminary protective measures prevent degradation during the melting and processing stages, preserving compositional integrity and molecular weight.

Inventive Principle:
Principle #10Preliminary action

4Ease of manufacture

If cellulose acetate is heated to melt-processing temperatures, then processability is improved, but article performance properties deteriorate

Engineering Contradiction:
ImproveprocessabilityVSAvoidarticle performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent carefully controls processing temperatures and times to achieve adequate processability while preserving the molecular weight and structural integrity necessary for article performance. This ensures the final product maintains required strength, flexibility, and durability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent includes heat stabilizers and molecular weight protective agents in the composition. These additives are incorporated beforehand to protect the polymer chains during thermal processing, ensuring the processed material retains sufficient molecular weight for adequate article performance.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cellulose acetate composition enables the production of biodegradable articles with improved processability and performance, meeting the need for environmentally friendly single-use products that can be easily recycled or composted, while maintaining performance standards.

Implementation Method 1

the material is melted into flowable form, processed and cooled to form a functional article

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

the material is melted into flowable form, processed and cooled to form a functional article

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS20240384063A1Melt-processable cellulose acetate compositions, melts and melt-formed articles made therefrom
Publication Date: 2024.11.21 EASTMAN CHEM CO
  • US20240384063A1 patent drawing

AI summary

A melt-processable cellulose acetate composition is disclosed. The melt-processable cellulose acetate composition of the present invention includes (i) cellulose acetate: (ii) a plasticizing amount of plasticizer; and (iii) fatty acid. Cellulose acetate melts and melt-formed articles are also described.