Cellulose Acetate Fiber Water Solubility

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Solution Overview

Problem

Conventional cellulose acetate fibers lack sufficient water solubility and biodegradability, leading to environmental load when left standing over time.

Innovation Solution

Cellulose acetate fibers with a total degree of acetyl substitution of 0.4 to 1.3 and a compositional distribution index of 2.0 or less, produced through electrospinning using a spinning dope dissolved in water or a water/mixed solvent, exhibit enhanced water solubility and biodegradability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cellulose acetate fiber is produced by dry spinning with high degree of substitution, then fiber strength and stability are improved, but water solubility and biodegradability deteriorate

Engineering Contradiction:
Improvefiber stabilityVSAvoidenvironmental load
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by precisely controlling the degree of acetyl substitution within the range of 0.4 to 1.3 and the compositional distribution index within 2.0 or less. These specific parameter ranges enable the fiber to achieve both sufficient stability and enhanced water solubility, allowing it to dissolve in rainwater after use and thereby reducing environmental load.

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If cellulose acetate with low degree of substitution is used to improve water solubility, then biodegradability is improved, but fiber strength and stability deteriorate

Engineering Contradiction:
Improveenvironmental loadVSAvoidfiber stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent resolves this contradiction by establishing an optimized parameter range for degree of substitution (0.4 to 1.3) that balances both water solubility and fiber stability. This specific range prevents the fiber from being too unstable while maintaining sufficient biodegradability and water solubility for environmental friendliness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the hydraulic principle by designing the fiber to dissolve in rainwater through controlled water solubility. The fiber structure and composition are engineered to allow gradual dissolution in water, enabling environmental degradation without requiring artificial intervention, thus reducing environmental load while maintaining stability during service.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Shape

If electrospinning method is used to produce fine fibers, then fiber diameter and surface area are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvefiber diameterVSAvoidmanufacturing process
Core Design Contradiction:
ShapeVSDevice complexity

Solution Approach 1:

The patent applies electrospinning technology to replace conventional mechanical spinning methods. This substitution enables the production of ultrafine fibers with controlled diameters and high surface area, enhancing the fiber's dissolving performance and environmental characteristics while maintaining manufacturing feasibility through established electrospinning equipment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting fibers and molded articles demonstrate excellent water solubility and biodegradability, reducing environmental impact and enabling applications like cigarette filters that dissolve in rainwater, minimizing waste.

Implementation Method 1

cellulose acetate is dissolved into dichloromethane, acetone or some other organic solvent in accordance with the degree of cellulose acetate substitution

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

the jetted out solution is dried with hot wind to be made into a fibrous state

Methodology Applied
Scientific EffectElectrohydrodynamics: Electrohydrodynamics

Implementation Method 3

the jetted out solution is dried with hot wind to be made into a fibrous state

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 4

cellulose acetate high in degree of substitution is hydrolyzed with an acid to be changed in total degree of substitution

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS10889916B2Cellulose acetate fiber, cellulose acetate fiber molded article, and methods respectively for producing said cellulose acetate fiber and said cellulose acetate fiber molded article
Publication Date: 2021.01.12 DAICEL CORP
  • US10889916B2 patent drawing

AI summary

Provided are a cellulose acetate fiber and a cellulose acetate fiber molded article which are excellent in water solubility and biodegradability and are small in load onto the natural environment even when allowed to stand still in the environment. The invention provides a cellulose acetate fiber containing cellulose acetate having a total degree of acetyl substitution of 0.4 to 1.3 and a compositional distribution index (CDI) of 2.0 or less as well as a cellulose acetate fiber molded article.