Cellulose-Coated Li-Ion Separator for Wettability and Thermal Shrinkage
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Conventional lithium-ion battery separators made from polyolefin materials suffer from poor wettability and high thermal shrinkage, which can lead to safety issues and battery failures, particularly at elevated temperatures, and existing solutions either compromise on thermal stability or scalability.
Innovation Solution
A multilayer separator structure comprising a polyolefin-based substrate layer, a polyolefin resin layer, and cellulose fiber-based outer layers, where the cellulose fibers are refined to nanometric sizes and the layers are stacked using lamination or hydraulic pressure methods, enhancing thermal stability and electrolyte retention while maintaining shutdown functionality.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a polyolefin layer is used as separator, then shutdown effect at elevated temperature is ensured, but wettability is poor
Solution Approach 1:
The patent applies composite materials by combining polyolefin substrate layers with cellulose-based outer layers. The cellulose layers provide hydrophilic properties that improve electrolyte wettability, while the polyolefin layers maintain the shutdown function. This composite structure resolves the contradiction by integrating materials with complementary properties.
Solution Approach 2:
The patent applies local quality by differentiating the properties of different layers within the separator structure. The inner polyolefin layers are designed for thermal shutdown functionality, while the outer cellulose layers are designed for electrolyte wettability. Each layer performs its specific function locally, resolving the contradiction between shutdown effect and wettability.
2Reliability
If polyolefin separator is used, then shutdown effect is achieved, but shrinking resistance at elevated temperature is weak
Solution Approach 1:
The patent combines polyolefin layers with cellulose-based layers to create a composite separator structure. The cellulose layers provide dimensional stability and resistance to thermal shrinkage, while the polyolefin layers provide shutdown functionality. This composite approach resolves the contradiction between achieving shutdown effect and maintaining shrinking resistance.
Solution Approach 2:
The patent changes the thermal parameters of the separator by incorporating cellulose materials with higher thermal stability than polyolefin alone. The cellulose layers raise the overall thermal stability parameter of the separator, enabling it to resist shrinkage at elevated temperatures while the polyolefin layers still provide shutdown at lower temperatures.
3Ease of manufacture
If conventional PE or PP separator is used, then manufacturing is simple, but dimensional stability at high temperature is poor
Solution Approach 1:
The patent uses composite materials combining polyolefin and cellulose layers. The cellulose layers provide high-temperature dimensional stability, while the polyolefin layers maintain ease of manufacturing through established processes. The composite structure achieves both goals by integrating materials that excel in different properties.
Solution Approach 2:
The patent segments the separator into multiple functional layers with distinct roles. The polyolefin layers are manufactured using simple, established processes, while the cellulose layers are added to provide thermal stability. This segmentation allows each layer to be optimized for its specific function while maintaining overall manufacturing feasibility.
4Reliability
If porous FBI membrane is used to improve wettability and thermal stability, then ionic conductivity is high, but fabrication process becomes complex
Solution Approach 1:
The patent uses commercially available cellulose-based materials and standard lamination processes instead of complex FBI membrane fabrication. The cellulose layers can be applied using simple coating or lamination techniques, avoiding the lengthy and complex fabrication steps required for porous FBI membranes while achieving similar or better performance.
Solution Approach 2:
The patent uses cellulose as an intermediary material that provides both wettability improvement and thermal stability without requiring complex fabrication processes. The cellulose layers act as a mediator between the polyolefin substrate and the electrolyte, providing hydrophilic pathways for ion transport while maintaining thermal stability through standard manufacturing processes.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The multilayer separator achieves improved thermal stability, reduced shrinkage, and enhanced electrolyte retention, effectively preventing dendrite penetration and short circuits, thus ensuring safer and more reliable lithium-ion battery performance.
Implementation Method 1
the wettability of this polyolefin layer is poor... The multilayer separator achieves improved thermal stability, reduced shrinkage, and enhanced electrolyte retention
Implementation Method 2
the separator has to maintain the aforementioned properties especially under hazardous conditions such as high temperatures... ensure a shutdown effect at elevated temperature
Implementation Method 3
The shrinking resistance of the separator are also weak due to the low melting down temperature of PE and PP... The multilayer separator achieves improved thermal stability, reduced shrinkage
Data Source
AI summary
A multilayer separator (200) for a lithium-ion battery having a structure including at least a polyolefin based substrate layer (204) forming the inner layer of the multilayer separator (200); a resin layer (203) stacked on both surface of the polyolefin substrate layer (204), the resin layer (203) being formed from a polyolefin; a cellulose fibers based outer layer (202) stacked on the surface of each resin layer (203).
