Cellulose Composite Stabilization in Acidic Beverages

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Solution Overview

Problem

Conventional cellulose composites with hydrophilic gums exhibit poor dispersion and suspension stability in acidic or high salt concentration aqueous media, leading to aggregation and separation issues in beverages like fruit juice and lactobacillus beverages.

Innovation Solution

A cellulose composite with crystalline cellulose and a branched anionic polysaccharide hydrophilic gum, such as psyllium seed gum, is kneaded to achieve a high storage elastic modulus, enhancing dispersion and suspension stability by forming a rigid network structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cellulose composite with hydrophilic gum is used, then it forms cellulose colloid in aqueous medium, but dispersion stability and suspension stability are insufficient in acidic or high salt concentration conditions

Engineering Contradiction:
Improvedispersion stabilityVSAvoidstability in acidic or high salt concentration
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent combines crystalline cellulose with a specific hydrophilic gum to create a composite material that leverages the strengths of both components. The crystalline cellulose provides structural integrity while the hydrophilic gum enhances dispersion stability, creating a composite that maintains stability in acidic and high salt concentration conditions where conventional single materials fail.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent specifies precise parameter ranges for the composite including crystalline cellulose content (5-50 wt%), hydrophilic gum content (50-95 wt%), particle size (0.1-10 μm), and molecular weight (10^4-10^6). By optimizing these parameters, the composite achieves enhanced dispersion stability and suspension stability in challenging environmental conditions while maintaining low viscosity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If micro fibrous cellulose is used to improve suspension stability, then it can fix particles in acidic or high salt concentration food, but the composite structure is not formed and suspension stability remains insufficient

Engineering Contradiction:
Improvesuspension stabilityVSAvoidcomposite structure formation
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent merges crystalline cellulose particles with hydrophilic gum molecules to form an integrated composite structure. The hydrophilic gum coats and binds the cellulose particles together, creating a unified composite that functions as a single stabilizing entity rather than separate components, thereby achieving both composite structure formation and enhanced suspension stability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The hydrophilic gum acts as an intermediary that bridges crystalline cellulose particles, facilitating their interaction and enabling the formation of a stable composite structure. The gum molecules adsorb onto cellulose particle surfaces and create inter-particle connections, mediating the formation of the composite network that provides suspension stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If bacterial cellulose with extremely thin and long shape is used, then dispersion stability is excellent, but storage elastic modulus becomes excessively high and texture becomes heavy

Engineering Contradiction:
Improvedispersion stabilityVSAvoidstorage elastic modulus
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies local quality by controlling the particle morphology of crystalline cellulose to have small, relatively spherical or oval shapes (0.1-10 μm diameter) rather than the extremely thin and long shape of bacterial cellulose. This localized structural modification at the particle level maintains dispersion stability while preventing excessive network formation that would lead to high storage elastic modulus and heavy texture.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes critical parameters including particle size (0.1-10 μm), shape (spherical or oval cross-section), and crystalline structure to optimize the balance between dispersion stability and storage elastic modulus. By controlling these parameters, the composite achieves adequate dispersion stability without the excessively high stiffness that characterizes bacterial cellulose systems.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cellulose composite maintains excellent dispersion and suspension stability in acidic or high salt conditions, preventing separation and aggregation, even with added water-insoluble components, thus improving the stability and texture of beverages.

Implementation Method 1

the cellulose composite has a storage elastic modulus (G') of 0.06 Pa or more in a water dispersion of pH 4

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 2

exhibits low viscosity, excellent dispersion stability and excellent suspension stability in an acidic or high salt concentration water dispersion

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

A cellulose composite comprising crystalline cellulose having an average polymerization degree of 500 or less and a hydrophilic gum wherein the hydrophilic gum is a branched anionic polysaccharide

Methodology Applied
Scientific EffectSteric stabilization:

Data Source

PatentEP2554587B1Cellulose composite
Publication Date: 2017.01.18 ASAHI KASEI CHEM CORP
  • EP2554587B1 patent drawingFigure 1
  • EP2554587B1 patent drawingFigure 2

AI summary

Disclosed is a cellulose composite which comprises cellulose and a hydrophilic gum, the cellulose composite giving a 1-mass% aqueous dispersion thereof which has a storage modulus (G') of 0.06 Pa or more when the pH thereof is 4.