Cellulosic Aggregators for Oil Spill Remediation

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Solution Overview

Problem

Current chemical herding agents and sorbents for oil spill remediation are limited by toxicity, effectiveness in windy or icy conditions, and slow degradation, and lack sufficient oil sorption capacity and buoyancy for in situ burning.

Innovation Solution

Development of solid, hydrophobic aggregators made from cellulosic particles modified with oleic acid and additional fatty acids, which are buoyant, have high oil sorption capacity, and can aggregate with crude oil to form a stable mass for in situ burning, even in adverse environmental conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If vegetable-based sorbents are used, then environmental friendliness is improved, but oil sorption capacity and buoyancy deteriorate

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidoil sorption capacity
Core Design Contradiction:
Object-generated harmful factorsVSQuantity of substance

Solution Approach 1:

The patent uses composite materials by combining vegetable-based sorbent particles with hydrophobic fatty acid modifiers (oleic acid and additional fatty acids). This creates a composite structure that maintains the environmental benefits of vegetable materials while adding the high oil sorption capacity and buoyancy characteristics of hydrophobic compounds. The fatty acids coat the vegetable particles, creating a dual-function material that resolves the contradiction between environmental friendliness and performance.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If mineral and synthetic sorbents are used, then oil sorption capacity and buoyancy are improved, but degradation speed and environmental impact deteriorate

Engineering Contradiction:
Improveoil sorption capacityVSAvoiddegradation speed
Core Design Contradiction:
Quantity of substanceVSDuration of action of stationary object

Solution Approach 1:

The patent changes the chemical parameters of vegetable-based sorbents by modifying them with hydrophobic fatty acids. This parameter change transforms the surface properties of the vegetable particles, dramatically increasing their oil sorption capacity and buoyancy to levels comparable with synthetic sorbents, while the underlying vegetable-based structure maintains biodegradability and environmental compatibility.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If herding agents are used, then oil coalescing is improved, but toxicity and environmental impact worsen

Engineering Contradiction:
Improveoil coalescingVSAvoidtoxicity
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The hydrophobic fatty acid-modified vegetable particles perform self-service by simultaneously providing both sorption and coalescing functions. The hydrophobic surface naturally repels water and attracts oil, causing oil droplets to coalesce onto the particle surfaces. This eliminates the need for separate chemical herding agents, reducing toxicity while maintaining effective oil coalescing capability.

Inventive Principle:
Principle #25Self-service

4Quantity of substance

If sorbents are used to capture oil, then oil sorption is improved, but effectiveness in windy and icy conditions deteriorates

Engineering Contradiction:
Improveoil sorptionVSAvoideffectiveness in adverse conditions
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The hydrophobic fatty acid modification provides a counteracting force against water penetration and ice formation. The strong hydrophobic effect created by the fatty acid coating on vegetable particles counterweights the adverse effects of wind-driven waves and icy conditions, allowing the sorbent to maintain its oil capture effectiveness in environments where traditional sorbents would fail.

Inventive Principle:
Principle #8Anti-weight (Counterweight)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The aggregators effectively capture and retain oil, allowing for stable slick formation and in situ burning, with enhanced buoyancy and biodegradability, and can operate in various environmental conditions including snow and ice.

Implementation Method 1

solid aggregators comprises water-buoyant, cellulosic particles having a hydrophobic surface modified by oleic acid and further modified by one or more additional fatty acids

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Implementation Method 2

aggregating a floating mass of aggregator and oil at the surface of the aqueous environment

Methodology Applied
Scientific EffectCoalescence: Coagulation

Data Source

PatentUS10695745B2Solid, hydrophobic aggregators and methods of making and using the same
Publication Date: 2020.06.30 BATTELLE MEMORIAL INST
  • US10695745B2 patent drawing
  • US10695745B2 patent drawing
  • US10695745B2 patent drawing

AI summary

Disclosed herein are aggregators that can be cellulosic particles having high oil sorption capacity, high hydrophobicity, high buoyancy in water, and an aggregation quality that can support environmental remediation of hydrocarbon spills (e.g., crude oil spills) by various cleanup strategies including burning, skimming, or bioremediation. Also disclosed are methods of making the materials and methods of using the materials for environmental remediation.