Cellulosic Material Treatment for Dimensional Stability

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Solution Overview

Problem

Modern preservation methods for cellulosic materials like wood face challenges in maintaining dimensional stability and resistance to water, insects, and fungi due to non-uniform water absorption and evaporation, leading to internal stresses and degradation.

Innovation Solution

A method involving a two-step treatment protocol using a water-soluble polyetheramine polymer followed by an epoxy-containing resin dispersion to impregnate cellulosic materials, enhancing hydrophobicity, dimensional stability, and resistance to fungi and insects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cellulosic material is treated with conventional preservation methods, then the material gains some protection from insects and rot, but the non-uniform water absorption and evaporation causes internal stresses leading to splitting, warping, and other dimensional instabilities

Engineering Contradiction:
Improveprotection from insects and rotVSAvoiddimensional stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameters of the treatment agent by using a two-step process: first impregnating with a polymer solution that has specific molecular weight and functional group characteristics, then treating with a modifying agent containing silane or aluminate compounds. This parameter change in the chemical composition enables uniform distribution without causing internal stresses, resolving the contradiction between protection and dimensional stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The treatment agent is formulated as a composite system combining a polymer base material with modifying agents (silane or aluminate compounds). This composite structure allows the treatment agent to simultaneously provide insect and rot protection while maintaining dimensional stability, as the different components work synergistically to prevent both biological degradation and water-induced stress

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If the cellulosic material absorbs water, then the material becomes more susceptible to degradation by organisms, but the water absorption causes swelling and subsequent shrinking that creates internal stresses

Engineering Contradiction:
Improvesusceptibility to organism degradationVSAvoiddimensional stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent introduces a polymer-based treatment agent as an intermediary substance that displaces water from the cellulosic material structure. This intermediary prevents water from serving as a pathway for organisms while also preventing the swelling and shrinking cycles that cause internal stresses, thereby addressing both harmful effects simultaneously

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The treatment significantly reduces water absorption, maintains dimensional stability, and improves resistance to fungi and insects, even after water leaching, demonstrating enhanced durability and water-repellency efficiency.

Implementation Method 1

impregnating the cellulosic material with an aqueous solution comprising a polymer, the polymer comprising a water-soluble polyetheramine

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

impregnating the cellulosic material with a modifying agent, the modifying agent comprising an aqueous dispersion comprising an epoxy-containing resin

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS11370919B2Treated porous material
Publication Date: 2022.06.28 DOW GLOBAL TECHNOLOGIES LLC

AI summary

A method for preparing a treated cellulosic material comprising: providing a cellulosic material; a first treatment protocol comprising impregnating the cellulosic material with an aqueous solution comprising a polymer, the polymer comprising a water-soluble polyetheramine; and a second treatment protocol comprising impregnating the cellulosic material with a modifying agent, the modifying agent comprising an aqueous dispersion comprising an epoxy-containing resin.