Correlated Electron Material Devices with Reduced Interfacial Impedance

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Solution Overview

Problem

Current integrated circuit devices, such as electronic switching devices, face challenges in achieving lower power consumption and higher speed while maintaining desirable impedance characteristics, particularly in memory and logic devices, due to issues with interfacial layer impedance and oxidation resistance.

Innovation Solution

The use of correlated electron materials (CEMs) with interfacial layers having reduced impedance, achieved through techniques like atomic layer deposition and nitrogen-rich environments to inhibit oxidation, allowing for efficient switching between conductive and insulative states without the need for filament formation, thereby preserving the 'born on' property of low impedance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional fabrication methods are used, then manufacturing process is simple, but interfacial layer impedance is high and oxidation resistance is poor

Engineering Contradiction:
Improveoxidation resistanceVSAvoidfabrication process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by performing nitrogen-rich environment annealing on the conductive substrate before depositing the correlated electron material. This pre-treatment modifies the substrate surface to inhibit oxidation during subsequent fabrication steps, thereby improving oxidation resistance without adding complex post-processing steps. The nitrogen diffusion into the substrate creates a protective environment that prevents oxygen exposure during material deposition.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs an inert atmosphere approach by using a nitrogen-rich environment during the annealing process. Nitrogen acts as a protective atmosphere that prevents oxidation of the conductive substrate and interfacial layers. This inert environment maintains low impedance at the interfaces while avoiding the formation of resistive oxide layers, thereby improving reliability without requiring vacuum or other complex protective atmospheres.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Use of energy by moving object

If high impedance interfacial layers are present, then device structure is simpler, but switching voltage is high and power consumption is high

Engineering Contradiction:
Improvepower consumptionVSAvoidswitching voltage
Core Design Contradiction:
Use of energy by moving objectVSEase of operation

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition and electrical properties of the interfacial layers through nitrogen-rich annealing. This treatment changes the impedance parameter of the interfaces from high to low, enabling efficient charge transfer between the conductive substrate and correlated electron material. The reduced interfacial impedance directly lowers the switching voltage required, thereby reducing power consumption while maintaining simple device structure.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If oxidation occurs at interfacial layers, then manufacturing process is simpler, but impedance increases and conductivity decreases

Engineering Contradiction:
Improveinterfacial conductivityVSAvoidmanufacturing process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent uses a nitrogen-rich inert atmosphere during annealing to prevent oxidation at the interfacial layers. This protective atmosphere inhibits oxygen exposure to the conductive substrate and correlated electron material interfaces, maintaining low impedance and high conductivity. The approach preserves manufacturing simplicity by using a single-step annealing process that simultaneously achieves oxidation protection and material activation without requiring additional deposition or coating steps.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables CEM devices to operate with significantly reduced switching voltages, enhancing performance, reducing complexity and cost, and maintaining high conductivity, thus addressing the limitations of existing technologies in power consumption and speed.

Implementation Method 1

nitrogen-rich environments to inhibit oxidation

Methodology Applied
Scientific EffectOxidation inhibition: Oxidation

Implementation Method 2

techniques like atomic layer deposition

Methodology Applied
Scientific EffectAtomic layer deposition: Chemical Vapour Deposition

Implementation Method 3

correlated electron materials (CEMs) with interfacial layers having reduced impedance

Methodology Applied
Scientific EffectElectron correlation:

Data Source

PatentUS10516110B2Fabrication of correlated electron material devices with reduced interfacial layer impedance
Publication Date: 2019.12.24 CERFE LABS INC
  • US10516110B2 patent drawing
  • US10516110B2 patent drawing
  • US10516110B2 patent drawing

AI summary

Subject matter disclosed herein may relate to fabrication of correlated electron materials used, for example, to perform a switching function. In embodiments, processes are described, which may be useful in avoiding formation of a potentially resistive oxide layer at an interfacial surface between a conductive substrate, for example, and a correlated electron material.