Tailoring Cement Composition for CO2 Injection Integrity

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Solution Overview

Problem

CO2 injection into wellbores can alter the chemical composition and mechanical properties of cement sheaths, leading to potential zonal isolation failures.

Innovation Solution

A method is developed to design and tailor a cement composition that can withstand CO2 exposure by predicting the depth of carbonation, determining the mechanical properties of carbonated and uncarbonated zones, and performing a near wellbore integrity analysis to ensure long-term zonal isolation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If CO2 is injected into the wellbore for oilfield operations or underground storage, then the CO2 can be stored or extracted, but the cement sheath is exposed to CO2 which alters its chemical composition and mechanical properties

Engineering Contradiction:
ImproveCO2 storage capacityVSAvoidzonal isolation integrity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the cement sheath by incorporating specific additives (e.g., calcium carbonate, silicate materials) and adjusting the water-to-cement ratio to create a CO2-resistant cement formulation that maintains mechanical properties under carbonation conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite cement material system combining traditional cement with CO2-resistant additives and admixtures to form a multi-phase composite that resists chemical degradation from CO2 exposure while maintaining structural integrity for zonal isolation

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If the cement sheath is exposed to CO2 over time, then CO2 storage or extraction can proceed, but the mechanical properties of the cement sheath deteriorate leading to potential isolation failures

Engineering Contradiction:
ImproveCO2 injection durationVSAvoidcement sheath mechanical strength
Core Design Contradiction:
Duration of action of moving objectVSStrength

Solution Approach 1:

The patent applies preliminary protective measures by pre-formulating the cement with CO2-resistant chemicals and admixtures before injection, creating a chemically resistant barrier that prevents or slows carbonation reactions during the extended CO2 injection period

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent incorporates buffering agents and chemical additives in the cement formulation that act as a protective cushion against CO2 attack, absorbing or neutralizing the harmful effects of CO2 exposure before they can significantly degrade the cement matrix

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Ease of manufacture

If a traditional cement composition is used in the wellbore, then the cement can be easily placed and cured, but it cannot withstand the chemical alteration from CO2 exposure

Engineering Contradiction:
Improvecement placement simplicityVSAvoidCO2 chemical alteration
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent adjusts key formulation parameters including water-to-cement ratio, additive concentrations, and curing conditions to achieve optimal balance between placement ease and CO2 resistance, ensuring the modified cement maintains workability while gaining chemical resistance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively predicts the mechanical response of the cement sheath to CO2 exposure, ensuring the cement composition can maintain zonal isolation and withstand wellbore loads over the life of the well.

Implementation Method 1

CO2 is injected into a wellbore, resulting in a cement sheath being exposed to the CO2, which in turn can alter chemical composition and mechanical properties of the cement sheath

Methodology Applied
Scientific EffectCarbonation reaction: Chemical Bonding

Data Source

PatentUS12306169B2Method to tailor cement composition to withstand carbon dioxide injection loads
Publication Date: 2025.05.20 HALLIBURTON ENERGY SERVICES INC
  • US12306169B2 patent drawing
  • US12306169B2 patent drawing
  • US12306169B2 patent drawing

AI summary

Methods of the present disclosure relate to tailoring cement compositions to withstand carbon dioxide injection. A method comprises predicting a depth of carbonation in a cement sheath; predicting spatially varying mechanical properties of the cement composition due to the carbonation; and determining a mechanical response of the cement sheath based on the spatially varying mechanical properties of the cement composition.