Cement Fluid Loss Control via pH-Sensitive Polymer Swelling

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Solution Overview

Problem

Conventional cement compositions used in well drilling experience fluid loss issues due to water outflow from cement slurries into porous geological strata, leading to increased viscosity, unsatisfactory packing, and potential strata collapse, which existing fluid loss control agents have not adequately addressed.

Innovation Solution

A cement composition incorporating a fluid loss control agent with a vinyl alcohol polymer and a crosslinking agent, where the swelling percentage is between 200% and 3600%, and the crosslinking agent forms a pH-sensitive crosslinked structure, effectively controlling fluid loss by maintaining slurry fluidity and ensuring proper cement hardening.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cement slurry is used for well drilling, then the slurry can be injected and hardened to protect the well wall, but water in the slurry flows out into porous geologic strata causing fluid loss, increased viscosity, and potential strata collapse

Engineering Contradiction:
Improvefluid loss controlVSAvoidwater outflow to geologic strata
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a fluid loss control agent as an intermediary substance between the cement slurry and the geologic strata. This agent forms a filter cake or barrier layer on the well wall surface, mediating the interaction between slurry and formation to prevent water from penetrating into porous strata while allowing the slurry to maintain its fluidity and proper water-cement ratio

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical composition parameters of the cement slurry by adding specific fluid loss control agents. These agents change the rheological and chemical parameters of the slurry system, creating a protective barrier that controls fluid loss without significantly altering the slurry's viscosity or hardening characteristics

Inventive Principle:
Principle #35Parameter changes

2Reliability

If fluid loss control agents are added to cement slurry, then water outflow is reduced, but the complexity of the cement composition increases

Engineering Contradiction:
Improvefluid loss controlVSAvoidcement composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs fluid loss control agents that perform multiple functions simultaneously: they control fluid loss by forming barrier layers, maintain slurry fluidity through rheological modification, and do not interfere with cement hardening. This multi-functionality reduces the need for multiple separate additives, thereby managing composition complexity while achieving comprehensive performance

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution significantly enhances fluid loss control, maintaining slurry fluidity and ensuring effective cement packing and hardening, thereby preventing strata collapse and improving the overall drilling process.

Implementation Method 1

the fluid loss control agent contains a vinyl alcohol polymer and a crosslinking agent, and a swelling percentage of the fluid loss control agent is 200% or more and 3,600% or less

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

a swelling percentage of the fluid loss control agent is 200% or more and 3,600% or less

Methodology Applied
Scientific EffectSwelling: Absorption (physical)

Implementation Method 3

using a polyvinyl alcohol based resin as a fluid loss control agent, which is capable of reducing fluid loss

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20240376006A1Cement composition, fluid loss control agent, and fluid loss control method for cement
Publication Date: 2024.11.14 KURARAY CO LTD
  • US20240376006A1 patent drawing
  • US20240376006A1 patent drawing

AI summary

A cement composition containing a fluid loss control agent and a cement, wherein the fluid loss control agent contains a vinyl alcohol polymer and a crosslinking agent, and a swelling percentage of the fluid loss control agent is 200% or more and 3,600% or less.