Cement-Free Clay Additive for Compressive Strength

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Solution Overview

Problem

Current construction materials, such as concrete, rely heavily on cement which requires significant energy and generates substantial CO2 emissions, and existing additives fail to effectively produce cement-free building materials with suitable workability and setting behavior using natural resources like clay.

Innovation Solution

An additive comprising a dispersing agent, such as aluminates, phosphates, or silicates, and a coagulating agent, like divalent metal salts, is used to create a cement-free building material by dispersing and agglomerating clay particles in an aqueous slurry, mimicking the properties of cement-based compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If cement is used as hydraulic binder in concrete, then strength and setting behavior are improved, but energy consumption and CO2 emissions increase

Engineering Contradiction:
Improvecompressive strengthVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The invention extracts and eliminates cement from the building material composition, replacing it with a combination of clay particles, dispersing agent, and coagulating agent. This removal of the harmful component (cement) while maintaining the essential function (binding and hardening) directly resolves the contradiction between strength and energy consumption/CO2 emissions.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical and physical parameters of the building material by using clay particles with specific surface area characteristics (greater than 0.5 m²/g) and controlling the dosage of dispersing and coagulating agents. These parameter changes enable cement-free compositions to achieve adequate strength and workability without the environmental costs of cement production.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If cement-free clay based compositions are produced, then energy consumption and CO2 emissions are reduced, but workability and setting behavior deteriorate

Engineering Contradiction:
Improveenergy consumptionVSAvoidworkability
Core Design Contradiction:
Use of energy by moving objectVSEase of operation

Solution Approach 1:

The invention introduces two intermediary substances: a dispersing agent (e.g., sodium hexametaphosphate, sodium silicate, or sodium aluminate) to prevent clay particle aggregation and maintain workability, and a coagulating agent (e.g., calcium chloride, calcium nitrate, or magnesium chloride) to control setting behavior. These intermediaries mediate between the clay particles and water, enabling cement-free compositions to achieve workability and setting characteristics similar to traditional cement-based materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite material system consisting of clay particles, dispersing agent, coagulating agent, and water. This composite approach combines multiple components with complementary functions to achieve the desired balance between energy efficiency and operational performance, overcoming the limitations of simple clay-based mixtures.

Inventive Principle:
Principle #40Composite materials

3Device complexity

If clay particles are used without dispersing and coagulating agents, then material composition is simplified, but compressive strength and workability decrease

Engineering Contradiction:
Improvematerial composition complexityVSAvoidcompressive strength
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

The invention optimizes specific parameters including clay particle surface area (greater than 0.5 m²/g), dispersing agent dosage (0.01-2% by weight based on clay weight), and coagulating agent dosage (0.01-2% by weight based on clay weight). These controlled parameter changes enable the system to achieve high compressive strength while maintaining a relatively simple overall composition.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additive enables the production of cement-free building materials with improved compressive strength and workability similar to traditional concrete or mortar, allowing for construction without adapting existing procedures or tools, while reducing energy consumption and CO2 emissions.

Implementation Method 1

a) a dispersing agent, selected from aluminates, aluminate precursors, phosphates, silicates and/or polyacrylates, which is capable of dispersing clay particles in an aqueous slurry

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

b) a coagulating agent, selected from salts of divalent metal cations, preferably salts of alkaline earth metals and/or iron, especially magnesium, calcium and/or iron salts, capable of causing clay particles to agglomerate in a aqueous slurry

Methodology Applied
Scientific EffectCoagulation: Coagulation

Data Source

PatentUS20230150876A1Additive for cement-free building materials
Publication Date: 2023.05.18 ETH ZURICH
  • US20230150876A1 patent drawing
  • US20230150876A1 patent drawing
  • US20230150876A1 patent drawing

AI summary

An additive for producing a hardenable building material, especially a mineral composition comprising clays, comprising or consisting of: a) a dispersing agent, selected from aluminates, aluminate precursors, phosphates, silicates and/or polyacrylates, which is capable of dispersing clay particles in an aqueous slurry, and b) a coagulating agent, selected from salts of divalent metal cations, preferably salts of alkaline earth metals and/or iron, especially magnesium, calcium and/or iron salts, capable of causing clay particles to agglomerate in a aqueous slurry.