Cement Composition with Nanoparticles for Lost Circulation

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Solution Overview

Problem

Conventional hydraulic cements are less effective in harsh environments, such as those with sea or brackish water, and subterranean formations with total losses, requiring a cement slurry that can be easily mixed and handle lost circulation applications effectively.

Innovation Solution

A cement composition comprising cementitious materials, an aqueous base fluid, nanoparticles (like nano-silica, nanocarbonate), synthetic clay, and a thixotropic modifier, with solid materials making up 0-40% of the total weight, allowing for improved rheological properties and effectiveness in harsh conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional hydraulic cement is used in harsh environments (sea water, brackish water, lost circulation formations), then the cement can be applied in various well conditions, but the effectiveness and performance of the cement is reduced

Engineering Contradiction:
Improveapplicability in various well conditionsVSAvoidcement effectiveness
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the cement slurry by incorporating specific additives (synthetic clay, nanoparticles, thixotropic modifiers) to change the rheological and mechanical properties, enabling the cement to maintain effectiveness in harsh environments while retaining adaptability to various well conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite cement material by combining conventional hydraulic cement with synthetic clay, nanoparticles (such as nanosilica), and thixotropic modifiers. This composite formulation enhances the cement's performance in lost circulation and harsh environments while maintaining its versatility across different well conditions

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional cement slurry is used, then the formulation is simple, but the mixing process becomes difficult in lost circulation applications

Engineering Contradiction:
Improveformulation simplicityVSAvoidmixing ease
Core Design Contradiction:
Device complexityVSEase of manufacture

Solution Approach 1:

The patent introduces thixotropic modifiers and synthetic clay as intermediary substances that facilitate the mixing process by controlling slurry viscosity and flow characteristics, making the cement easier to pump and place in lost circulation zones while maintaining a relatively simple overall formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If cement with high solid material content is used, then the mechanical strength is improved, but the rheological properties and pumpability are worsened

Engineering Contradiction:
Improvecompressive strengthVSAvoidpumpability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent optimizes the solid material content parameter within a specific range (providing balance between strength and pumpability) and uses thixotropic modifiers to dynamically change the rheological properties, allowing the slurry to be pumpable at low shear rates while achieving high strength after setting

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs thixotropic modifiers that provide time-dependent and shear-rate-dependent viscosity changes, allowing the cement slurry to be easily pumped (low viscosity under shear) and then set with high strength (high viscosity at rest) without requiring extreme solid material content

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cement composition provides improved mechanical properties, such as compressive strength and shear-rate dependent viscosity, enabling effective cementing in lost circulation applications and harsh environments, with enhanced performance in both fresh and saltwater conditions.

Implementation Method 1

the rheological properties of the cement composition are shear-rate dependent. The viscosity of the non-Newtonian fluid decreases with an increase in shear rate

Methodology Applied
Scientific EffectShear thinning: Shear Thinning

Implementation Method 2

a thixotropic modifier... The viscosity of the non-Newtonian fluid decreases with an increase in shear rate

Methodology Applied
Scientific EffectThixotropy: Thixotropy

Data Source

PatentUS10479923B2Cement composition for lost circulation application and method of cementing
Publication Date: 2019.11.19 HALLIBURTON ENERGY SERVICES INC
  • US10479923B2 patent drawing

AI summary

A method of cementing a subterranean formation includes providing a cement composition comprising cementitious material, aqueous base fluid, nanoparticles, synthetic clay, and a thixotropic modifier, where the solid materials are about 0 wt % to about 40 wt % of the total weight of the cement composition; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. Cement compositions include cementitious material, aqueous base fluid, nanoparticles, synthetic clay, and a thixotropic modifier.