Cement Slurry Composition with Micelle Network for High-Temperature Well Cementing

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Solution Overview

Problem

Conventional cement slurry compositions for wells face challenges with segregation resistance and crack prevention, especially at high temperatures, where they often lose fluidity and become prone to material separation and cracking.

Innovation Solution

A cement slurry composition combining a hydraulic cement material with specific water-soluble low molecular weight compounds, forming thread-like micelles that aggregate to create a high viscoelastic network, enhancing segregation resistance and fluidity at high temperatures, and allowing for easy pumping and filling without cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cement slurry compositions are used, then basic cementing function is achieved, but segregation and cracking occur easily

Engineering Contradiction:
Improvesegregation resistanceVSAvoidadditive combination complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention uses a composite rheology modifier system combining cationic surfactants with long hydrocarbon chains (18+ carbon atoms) and anionic aromatic compounds or brominated compounds. This composite approach creates synergistic effects that significantly improve segregation resistance and crack prevention compared to single additive systems, while the specific combination provides enhanced performance in high-temperature well cementing applications.

Inventive Principle:
Principle #40Composite materials

2Productivity

If cement slurry is pumped and filled rapidly, then productivity is improved, but fluidity is lost and cracking occurs

Engineering Contradiction:
Improvefilling speedVSAvoidfluidity maintenance
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The rheology modifier system dynamically adjusts the slurry's rheological properties during pumping and filling operations. The cationic surfactant-anionic compound combination creates a adaptive network structure that maintains fluidity during rapid pumping while preventing segregation and cracking during the filling process, allowing high productivity without sacrificing composition stability.

Inventive Principle:
Principle #15Dynamics

3Strength

If high-density additives are used to improve cement strength, then strength is improved, but segregation resistance deteriorates

Engineering Contradiction:
Improvecement strengthVSAvoidsegregation resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The cationic surfactant-anionic compound combination acts as an intermediary mechanism that mediates between the conflicting requirements of strength enhancement and segregation prevention. This rheology modifier system creates a protective network that allows high-density additives to improve strength while simultaneously preventing material segregation, resolving the contradiction between these two performance requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits excellent segregation resistance, fluidity, and viscoelasticity, preventing material separation and cracking, even at elevated temperatures, making it suitable for well cementing applications.

Implementation Method 1

forming thread-like micelles that aggregate to create a high viscoelastic network

Methodology Applied
Scientific EffectMicelle formation: Colloid

Implementation Method 2

create a high viscoelastic network, enhancing segregation resistance and fluidity at high temperatures

Methodology Applied
Scientific EffectViscoelasticity: Viscoelasticity

Implementation Method 3

the compound (A) selected from cationic surfactants and the compound (B) selected from anionic aromatic compounds; or (II) the compound (A) selected from cationic surfactants and the compound (B) selected from brominated compounds

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS8728229B2Cement slurry composition
Publication Date: 2014.05.20 KAO CORP

AI summary

The present invention provides a cement slurry composition, containing a hydraulic cement material, (A) a first water-soluble low molecular weight compound and (B) a second water-soluble low molecular weight compound differing from the compound (A), wherein a combination of the compounds (A) and (B) is (I) the compound (A) selected from cationic surfactants and the compound (B) selected from anionic aromatic compounds; or (II) the compound (A) selected from cationic surfactants and the compound (B) selected from brominated compounds, and in the compound (A), a ratio of compounds having a hydrocarbon group of 18 or more carbon atoms is not less than 45% by weight.