Cement Spacer Fluid with Quaternary Surfactant and Proppant

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Solution Overview

Problem

Cement plugs in wellbore operations often fail to set in their intended place due to density swapping between cement slurries and drilling fluids, leading to contamination and compromised integrity, necessitating an effective alternative for fluid separation.

Innovation Solution

A cement spacer fluid comprising a carrier fluid, a quaternary surfactant, and a proppant is injected into the wellbore to minimize density swapping, forming a gel that supports the cement slurry and prevents mixing with wellbore fluids, ensuring proper placement and setting of the cement plug.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cement slurry is pumped down the drill pipe to form a plug, then the cement plug can be formed to secure a seal or provide a base for directional change, but density swapping occurs between the cement slurry and drilling fluid causing the cement slurry to mix with wellbore fluids and fail to set in its intended place

Engineering Contradiction:
Improvecement plug setting reliabilityVSAvoidfluid separation stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

A spacer fluid is introduced as an intermediary substance between the drilling fluid and cement slurry. This spacer fluid has a density intermediate between the two fluids and forms a stable barrier that prevents direct contact and mixing between the drilling fluid and cement slurry, thereby eliminating the density swapping problem while allowing the cement slurry to set reliably in its intended location

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The wellbore fluid column is segmented into distinct layers: drilling fluid at the bottom, spacer fluid in the middle, and cement slurry at the top. This segmentation creates clear boundaries between the fluids, preventing intermixing and ensuring the cement slurry remains isolated and stable until it sets, thus resolving the contradiction between reliability and compositional stability

Inventive Principle:
Principle #1Segmentation

2Stability of the object's composition

If known cement spacers are used to separate drilling fluids from cement slurries, then some fluid separation is achieved, but the spacers allow mixing and remixing of the fluids compromising the integrity of the cement plug

Engineering Contradiction:
Improvefluid separation effectivenessVSAvoidcement plug integrity
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The spacer fluid's density is specifically controlled to be intermediate between the drilling fluid and cement slurry, creating a stable density gradient that prevents mixing. Additionally, the spacer fluid contains viscosifiers and surfactants that modify its rheological properties to maintain stable layering and prevent remixing, thereby achieving both effective separation and integrity preservation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The spacer fluid is formulated as a composite system combining carrier fluid, viscosifiers, surfactants, and proppants. This composite formulation provides multiple functions: density control for layering, viscosity modification for stable separation, surfactant-based barrier properties to prevent mixing, and proppant particles that reinforce the spacer fluid's ability to maintain separation and prevent fluid communication between the drilling fluid and cement slurry

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the cement spacer fluid effectively suppresses fluid mixing and remixing, enhances segregation, and prevents cement plug set-up failures, improving the quality and reliability of plug cementing operations by maintaining the integrity of the cement plug at its intended location.

Implementation Method 1

a quaternary surfactant having a cation of R1 R2 R3 R4N+ and an anion

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

about 0.05 to about 10 wt % of a viscosifier

Methodology Applied
Scientific EffectViscosifier:

Implementation Method 3

about 1 to about 65 wt % of a proppant

Methodology Applied
Scientific EffectProppant:

Implementation Method 4

The gel has a strong enough structure to support the cement slurry

Methodology Applied
Scientific EffectGel: Gel

Data Source

PatentUS10480278B1Cement spacer fluid comprising quaternary surfactant, viscosifier, and proppant
Publication Date: 2019.11.19 BAKER HUGHES CO
  • US10480278B1 patent drawing

AI summary

A method of cementing a wellbore penetrating a subterranean formation comprises: injecting into the wellbore a cement spacer fluid comprising a carrier fluid, a quaternary surfactant, a viscosifier, and a proppant; injecting a cement slurry into the wellbore; and allowing the cement slurry to set.