3D-Printed Cementitious Mixture Rheology Control

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Solution Overview

Problem

Existing 3D printing technologies face challenges with hydraulic binders having short initial setting times, which lead to material buildup in equipment and limited operational flexibility, while also requiring high printing speed and strong interlayer bonding for structural stability.

Innovation Solution

A dry cementitious material mixture for 3D printing comprising hydraulic cement, viscosity-enhancing admixtures, and clay, eliminating the need for additional admixtures at the deposition head, providing a consistent and stable fresh mortar or concrete composition with increased yield strength and thixotropy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a hydraulic binder with a short initial setting time is used, then the mechanical stability of deposited layers is improved, but material buildup in mixing devices and pumps increases

Engineering Contradiction:
Improvemechanical stability of deposited layersVSAvoidmaterial buildup in equipment
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent changes the rheological parameters of the fresh concrete by adding viscosity-enhancing admixtures (cellulose ethers, associative thickeners) to modify the flow behavior and yield stress, allowing the material to remain pumpable while developing sufficient strength to support subsequent layers without excessive buildup

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system combining hydraulic binder, viscosity-enhancing admixtures, and specific aggregate distributions to achieve a material that simultaneously provides early strength development and reduced adhesion to equipment surfaces

Inventive Principle:
Principle #40Composite materials

2Speed

If a hydraulic binder with a short initial setting time is used, then the printing speed is improved, but the operational flexibility is reduced

Engineering Contradiction:
Improveprinting speedVSAvoidoperational flexibility
Core Design Contradiction:
SpeedVSAdaptability or versatility

Solution Approach 1:

The patent modifies the rheological parameters (yield stress, plastic viscosity) through viscosity-enhancing admixtures to extend the working time window, allowing slower printing speeds while maintaining layer stability, thus improving operational flexibility without sacrificing printing efficiency

Inventive Principle:
Principle #35Parameter changes

3Strength

If a hydraulic binder with a short initial setting time is used, then the interlayer adhesion is improved, but the time for adjustments during construction is reduced

Engineering Contradiction:
Improveinterlayer adhesionVSAvoidtime for adjustments during construction
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The patent adjusts the rheological parameters to achieve optimal yield stress values that maintain layer shape and support subsequent layers while extending the setting time, providing a wider window for construction adjustments without compromising interlayer bonding quality

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If the fresh concrete has low yield stress for good pumpability, then the ease of operation is improved, but the mechanical stability of deposited layers deteriorates

Engineering Contradiction:
ImprovepumpabilityVSAvoidmechanical stability of deposited layers
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent optimizes the yield stress parameter to a specific range that balances pumpability and layer stability, using viscosity-enhancing admixtures to achieve sufficient yield stress for mechanical stability while maintaining flowability for easy pumping and deposition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a dynamic rheological behavior where the concrete exhibits shear-thinning properties, allowing it to flow easily during pumping and deposition then rapidly develop yield stress to support subsequent layers, effectively adapting its mechanical properties to different operational phases

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables non-stop continuous 3D printing with improved mechanical stability, reduced material buildup, and enhanced operational flexibility, allowing for high-strength structures with consistent quality and cost savings.

Implementation Method 1

The at least one viscosity enhancing admixture and the clay are present in an amount to increase the yield stress of the fresh mortar or concrete composition immediately after placing and/or after a defined period of time

Methodology Applied
Scientific EffectThixotropy: Thixotropy

Implementation Method 2

the combined amount of the at least one viscosity enhancing admixture and of the clay is selected in order to achieve a yield stress of 0.5-1.5 kPa, preferably 0.5-3 kPa, immediately after placing the fresh mortar or concrete composition

Methodology Applied
Scientific EffectYield stress development:

Implementation Method 3

3d printed elements also require a strong bonding strength between the deposited layers

Methodology Applied
Scientific EffectHydration: Mineral Hydration

Data Source

PatentUS20240383811A1Dry cementitious material mixture for 3d-printing
Publication Date: 2024.11.21 HOLCIM TECHNOLOGY LTD
  • US20240383811A1 patent drawing
  • US20240383811A1 patent drawing
  • US20240383811A1 patent drawing

AI summary

A dry cementitious material mixture for 3D-printing, includes a hydraulic cement, at least one viscosity enhancing admixture, and clay and optionally aggregates, wherein the at least one viscosity enhancing admixture is present in an amount of 0.05-1.5% by weight based on the hydraulic cement and the clay is present in an amount of 0.01-5.0% by weight based on the hydraulic cement.