Ceramic Catalyst Modules With Resistance Heating for Hydrogen Reforming

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing hydrogen production methods, particularly those based on hydrocarbons, have significant carbon dioxide emissions and inefficiencies, and there is a need for more efficient and flexible processes that reduce emissions and improve operational flexibility.

Innovation Solution

A process utilizing ceramic catalyst modules with resistance heating elements for serial flow, enabling precise temperature control and flexible operation, which are designed for endothermic reactions such as reforming, and eliminate flue gas emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional hydrocarbon-based hydrogen production processes are used, then large-scale hydrogen production is achieved, but significant carbon dioxide emissions occur

Engineering Contradiction:
Improvehydrogen production scaleVSAvoidcarbon dioxide emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the fundamental parameter of heating method from combustion-based to electric resistance heating, enabling precise temperature control and eliminating flue gas emissions while maintaining high-temperature reforming conditions necessary for efficient hydrogen production

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention extracts and eliminates the harmful combustion process and flue gas generation from the system by using electric resistance heating elements embedded in ceramic catalyst modules, separating the heating function from the catalytic reforming function

Inventive Principle:
Principle #2Taking out (Extraction)

2Productivity

If conventional hydrogen production processes are used, then established production capacity is achieved, but operational flexibility and efficiency are limited

Engineering Contradiction:
Improveproduction capacityVSAvoidoperational flexibility
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The invention introduces dynamic control capabilities through electric resistance heating elements that can be independently controlled, allowing rapid adjustment of temperature and process conditions to optimize for different operating scenarios, feedstocks, and product requirements

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The invention segments the catalyst into modular ceramic modules with embedded heating elements, allowing independent control and optimization of different reaction zones, enabling flexible process configuration and rapid start-up/shutdown operations

Inventive Principle:
Principle #1Segmentation

3Temperature

If conventional heating methods are used in catalytic reforming, then high temperature conditions are achieved, but flue gas emissions and heat loss occur

Engineering Contradiction:
Improvereaction temperatureVSAvoidflue gas emissions
Core Design Contradiction:
TemperatureVSObject-generated harmful factors

Solution Approach 1:

The invention replaces the mechanical/chemical combustion heating system with an electric resistance heating system embedded directly in the catalyst modules, eliminating the need for external burners and flue gas management while providing direct, efficient heat transfer to the reaction zone

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention nests the electric resistance heating elements within the ceramic catalyst modules themselves, creating a integrated structure where the heating function is embedded within the catalytic function, enabling direct heat transfer and eliminating heat loss to the environment

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves high efficiency, flexibility, and reduced carbon dioxide emissions by using electrically heated ceramic catalyst modules with precise temperature control, allowing rapid start-up and shutdown, and minimizing maintenance.

Implementation Method 1

the catalyst is heated using electrical energy and is provided in a plurality of ceramic catalyst modules... resistance heating elements are guided through the catalyst modules

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

bringing it into contact with a catalyst in the reactor to obtain (elemental or molecular) hydrogen... the catalyst modules are designed for serial flow with the reaction feed

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

Suitable bridging technologies can be used... These bridging technologies include, in particular, the recovery and storage or utilization of carbon dioxide... Hydrogen produced in this way is also referred to as 'blue' hydrogen

Methodology Applied
Scientific EffectEndothermic reaction: Endothermic Reaction

Data Source

PatentEP4585558A1Method and installation for producing a process product
Publication Date: 2025.07.16 LINDE AG
  • EP4585558A1 patent drawingFigure 1
  • EP4585558A1 patent drawingFigure 2
  • EP4585558A1 patent drawingFigure 3

AI summary

A method for producing a process product is proposed, which comprises feeding a reaction feed (1) to a reactor (100) and contacting it with a catalyst in the reactor (100) to obtain hydrogen. The catalyst is heated using electrical energy and is provided in a plurality of ceramic catalyst modules (110, 120, 130), through each of which resistance heating elements (113, 123, 133) are passed. The catalyst modules (110, 120, 130) are configured for serial flow with the reaction feed (1). A plant for carrying out the method is also proposed.