Ceramic-Coated Proppant Strength and Durability

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Solution Overview

Problem

Conventional proppants used in hydraulic fracturing face challenges such as inadequate strength and chemical resistance, leading to fracture closure and reduced hydrocarbon production due to crushing and fines generation, which are exacerbated by resin coatings that degrade over time and become brittle under heat.

Innovation Solution

Ceramic-coated proppants are developed by applying a ceramic matrix composite (CMC) coating to core proppants, using materials like calcined clay, bauxite, silica, or alumina, to enhance strength and chemical resistance, and incorporating reinforcing fibers to improve crack resistance and fracture toughness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If resin coatings are applied to proppants to improve strength, then proppant strength is improved, but the coating degrades over time and becomes brittle under heat

Engineering Contradiction:
Improveproppant strengthVSAvoidcoating durability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the material parameter from organic resin to inorganic ceramic coating. The ceramic coating is applied and then sintered at high temperature (900-1500°C) to create a stable, heat-resistant layer that maintains its properties under downhole conditions, eliminating the degradation issues of resin coatings.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses ceramic matrix composite (CMC) materials consisting of ceramic particles embedded in a ceramic matrix. This composite structure provides both the strength enhancement needed and the thermal stability required for long-term reliability in high-temperature formation environments.

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional proppants are used in high-stress formations, then fracture closure occurs, but proppant crush strength is insufficient

Engineering Contradiction:
Improvecrush strengthVSAvoidfracture maintenance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies a ceramic coating to conventional proppants (like sand) to create a composite structure. The ceramic outer layer provides high crush strength and fracture toughness, allowing the proppant to withstand high formation closure stresses without crushing, while the inner proppant core maintains the necessary permeability and fracture conductivity.

Inventive Principle:
Principle #40Composite materials

3Reliability

If proppants are coated with ceramic to improve strength and chemical resistance, then durability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvechemical resistanceVSAvoidcoating process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The ceramic coating process is designed to be self-adhering through a slurry application method. The coating slurry is applied to the proppant surface and then sintered, where the ceramic material fuses to the proppant core without requiring additional bonding agents or complex multi-step processes, simplifying manufacturing while achieving the desired chemical resistance.

Inventive Principle:
Principle #25Self-service

Data Source

PatentUS11578263B2Ceramic-coated proppant
Publication Date: 2023.02.14 SAUDI ARABIAN OIL CO
  • US11578263B2 patent drawing
  • US11578263B2 patent drawing
  • US11578263B2 patent drawing

AI summary

A method of forming a ceramic-coated proppant, including receiving a proppant or particle and coating the proppant or particle with ceramic to give a ceramic coating on the proppant or particle. A method of hydraulic fracturing a geological formation with the ceramic-coated proppant.