Ceramic Coating Removal via Caustic Immersion and Water Jet Blasting
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Solution Overview
Problem
Current methods for removing ceramic coatings from thermal barrier coated metallic articles, such as those used in gas turbine engines, are inadequate as they either fail to fully remove the coating or damage the underlying metallic bond coating, leading to inefficiencies and increased costs due to the need for reapplication of bond coatings.
Innovation Solution
A method involving immersion in a caustic solution followed by water jet blasting, tailored to specific ceramic microstructures, to selectively remove ceramic coatings without damaging the metallic bond coating, allowing for precise removal and reapplication without compromising the bond coating's integrity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Manufacturing precision
If conventional water jet blasting is used to remove ceramic coating, then complete removal of the ceramic coating is achieved, but the metallic bond coating is removed or eroded
Solution Approach 1:
The invention segments the ceramic coating removal process into two distinct stages: first using caustic solution to chemically weaken and remove the ceramic coating, then using water jet blasting only to remove residual ceramic material. This segmentation allows each method to be optimized for its specific function, preventing the metallic bond coating damage that occurs when water jet blasting is used alone for complete removal.
Solution Approach 2:
The caustic solution acts as an intermediary substance that facilitates the removal process. It chemically attacks and weakens the ceramic coating structure, creating a compromised state that allows subsequent water jet blasting to remove only residual ceramic material without directly impacting the metallic bond coating. The intermediary chemical treatment mediates between the aggressive mechanical removal and the protective requirement for the bond coating.
2Manufacturing precision
If caustic solution is used to remove ceramic coating, then the ceramic coating is weakened and removed, but the process is ineffective for dense lamellae microstructure coatings
Solution Approach 1:
The invention creates a universal removal process that works for both porous columnar grain and dense lamellae microstructure ceramic coatings. The two-stage approach combines chemical treatment (effective for porous structures) with mechanical treatment (effective for dense structures), making the overall process adaptable to different ceramic microstructures. The water jet blasting stage provides the versatility needed to handle dense coatings that resist chemical attack alone.
Solution Approach 2:
The invention changes the parameters of the removal process by introducing chemical treatment parameters (caustic solution concentration, temperature, immersion time) followed by mechanical treatment parameters (water pressure, jet velocity). This parameter transformation allows the process to adapt to different ceramic microstructures - the chemical parameters address porous structures while the mechanical parameters address dense structures, achieving broad versatility.
3Manufacturing precision
If repeated water jet blasting is used to completely remove ceramic coating, then complete removal is achieved, but the metallic bond coating is eroded and surface roughness is reduced
Solution Approach 1:
The caustic solution treatment is performed as a preliminary action before water jet blasting. This preliminary chemical treatment weakens and removes the bulk of the ceramic coating, reducing the amount of material that subsequent water jet blasting needs to remove. By performing the aggressive removal action first, the need for repeated water jet blasting is eliminated, preventing erosion of the metallic bond coating.
Solution Approach 2:
The invention replaces purely mechanical removal (water jet blasting) with a combined chemical-mechanical system. The chemical action of the caustic solution substitutes for the mechanical force that would otherwise be required to remove dense ceramic material through repeated blasting. This substitution reduces the cumulative mechanical stress on the metallic bond coating, preventing material loss and surface roughness reduction.
4Manufacturing precision
If water jet blasting is used on convex surfaces, then ceramic coating removal is difficult, but prolonged blasting damages the metallic bond coating
Solution Approach 1:
The removal process is segmented into chemical treatment followed by brief mechanical treatment. The caustic solution penetrates and weakens the ceramic coating on convex surfaces during immersion, eliminating the need for prolonged water jet blasting. This segmentation reduces the duration of mechanical action required, preventing bond coating damage while achieving complete ceramic removal from difficult-to-reach convex surfaces.
Solution Approach 2:
The caustic solution serves as an intermediary that facilitates access to and removal of ceramic coating on convex surfaces. It chemically penetrates the ceramic structure regardless of surface geometry, weakening the bond between ceramic and metal. This intermediary chemical action eliminates the need for extended mechanical blasting time on convex surfaces, reducing the duration of harmful mechanical action while achieving complete removal.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This method effectively removes ceramic coatings of varying microstructures without damaging the metallic bond coating, enabling cost-effective reapplication and maintaining the surface roughness and composition of the bond coating, thus reducing operational expenses and improving coating efficiency.
Implementation Method 1
the caustic solution is effective in permeating through a ceramic coating with a columnar grain microstructure to weaken an oxide layer between the metallic bond coating and the columnar grain ceramic coating
Implementation Method 2
water jet blasting the first portion of the ceramic coated metallic article to remove the ceramic coating
Data Source
AI summary
A method of removing a ceramic coating from a ceramic coated metallic article without damaging the metallic bond coating, the metallic article having a first and second portions, each of the portions comprising a metallic bond coating and a ceramic coating on the metallic bond coating, the ceramic coating on the second portion being less porous than the ceramic coating on the first portion. The method comprises the steps of a) immersing the ceramic coated metallic article in a caustic solution; b) maintaining the ceramic coated metallic article in the caustic solution at atmospheric pressure for a predetermined time period and at a predetermined temperature; c) removing the ceramic coated metallic article from the caustic solution; d) rinsing the ceramic coated metallic article in water at ambient temperature; e) water jet blasting the first portion of the metallic article to remove the ceramic coating; and f) water jet blasting the second portion of the metallic article to remove the ceramic coating.


