Multilayer Ceramic Electrode Structure to Prevent Peeling
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Solution Overview
Problem
Ceramic electronic devices, such as multilayer ceramic capacitors, face issues with external electrodes peeling off due to insufficient flexibility and adhesion, particularly when the base metal layer is not fully formed or adheres poorly to the chip surface.
Innovation Solution
A multilayer structure is implemented with a first metal layer containing a second metal with a lower Young's modulus, which is deposited using sputtering or vapor deposition to enhance flexibility and adhesion, and a plated layer is formed on this metal layer to prevent peeling, ensuring contact with the chip surface even where the base layer is not present.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Ease of manufacture
If a simple metal layer is used for external electrodes, then the manufacturing process is simple, but the external electrodes peel from the multilayer chip
Solution Approach 1:
The patent applies composite materials by creating a multi-layer metal structure consisting of a base metal layer, an intermediate metal layer, and a plated layer. This composite structure combines the advantages of different metals: the base layer provides adhesion to the ceramic chip, the intermediate layer provides flexibility and stress relief, and the plated layer provides conductivity and solderability. This resolves the contradiction by maintaining manufacturing simplicity while dramatically improving external electrode adhesion and preventing peeling.
Solution Approach 2:
The patent changes the physical and chemical parameters of the metal layers, specifically controlling the thickness, composition, and mechanical properties (Young's modulus) of each layer. The intermediate layer is designed with specific parameter ranges to provide optimal flexibility and stress distribution. By carefully adjusting these parameters, the patent achieves both strong adhesion and flexibility without complicating the manufacturing process.
2Strength
If a metal layer with high Young's modulus is used, then the external electrodes have high strength, but the external electrodes are prone to peeling
Solution Approach 1:
The patent changes the mechanical parameter (Young's modulus) of the metal layers by introducing an intermediate layer with different elastic properties. This intermediate layer acts as a stress buffer, reducing the stress concentration at the interface between the rigid base metal layer and the ceramic chip. The parameter optimization of the intermediate layer's thickness and composition achieves both strength and adhesion without requiring a single material to satisfy conflicting requirements.
Solution Approach 2:
The patent uses composite materials to combine a high-strength base metal layer with a more flexible intermediate layer. This composite structure allows the external electrode to maintain high overall strength while the intermediate layer prevents peeling by accommodating thermal expansion differences and reducing stress concentration. The composite approach resolves the contradiction between strength and adhesion by distributing different functions across multiple layers.
3Reliability
If a multi-layer metal structure is used, then peeling is suppressed, but the manufacturing process becomes more complex
Solution Approach 1:
The patent applies preliminary action by forming the base metal layer and intermediate metal layer on the ceramic chip before applying the plated layer. This sequence ensures that the adhesion-critical layers are established first on the chip surface, and subsequent plating processes build upon this foundation. By preparing the metal substrate structure in advance, the patent simplifies the overall manufacturing process despite the multi-layer structure, as each subsequent layer builds on the previous one in a systematic manner.
Solution Approach 2:
The intermediate metal layer serves as an intermediary between the base metal layer and the plated layer, as well as between the metal electrode and the ceramic chip. This intermediary layer facilitates adhesion, provides stress relief, and enables the plating process to proceed uniformly. The intermediary approach resolves the complexity issue by creating a systematic, modular structure where each layer has a specific function, making the manufacturing process more controllable and repeatable despite the increased number of layers.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution effectively suppresses peeling of external electrodes by increasing the flexibility of the first metal layer and ensuring strong adhesion, maintaining the integrity of the ceramic electronic device.
Implementation Method 1
forming a metal layer that contacts the multilayer chip and is electrically connected to the internal electrode layers exposed to the two surface regions, by sputtering or vapor deposition
Implementation Method 2
forming a metal layer that contacts the multilayer chip and is electrically connected to the internal electrode layers exposed to the two surface regions, by sputtering or vapor deposition
Data Source
AI summary
A ceramic electronic component includes a multilayer chip having a structure in which dielectric layers and internal electrode layers are alternately stacked, a main component of the dielectric layers being ceramic, the internal electrode layers being alternately exposed to two surface regions of the multilayer chip, and external electrodes, each of which is provided on each of the two surface regions. At least a part of each of the external electrodes has a first metal layer contacting the multilayer chip and a plated layer provided on the first metal layer. The first metal layer includes a first metal and a second metal having a Young's modulus smaller than that of the first metal.


