Ceramic Matrix Composite Feed Injector Tip for Gasification

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Solution Overview

Problem

Gasification system feed injectors face issues with cracking, corrosion, and erosion due to high temperatures and corrosive syngas, leading to reduced lifespan and increased maintenance costs, including the complexity and cost of closed-loop water cooling systems and frequent replacements.

Innovation Solution

The feed injector features an outer tube tip portion made of ceramic matrix composite, sintered Silicon Carbide, or sintered Silicon Nitride, which provides improved resistance to high temperatures, thermal shock, corrosion, and erosion, eliminating the need for a water cooling system and simplifying replacement processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a closed-loop water cooling system is used to protect the feed injector tip from high temperatures, then the feed injector can operate at high temperatures, but the system becomes complex to manufacture and costly to operate

Engineering Contradiction:
Improveresistance to high temperaturesVSAvoidcooling system complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The feed injector tip is made from a ceramic matrix composite material that inherently withstands high temperatures up to about 2600° F. (1427° C.) without requiring external cooling systems. This composite material combines the benefits of ceramic heat resistance with the toughness of fiber reinforcement, eliminating the need for complex water cooling infrastructure while maintaining operational integrity at extreme temperatures.

Inventive Principle:
Principle #40Composite materials

2Temperature

If a closed-loop water cooling system is used to protect the feed injector tip from high temperatures, then the feed injector can operate at high temperatures, but the operating cost increases

Engineering Contradiction:
Improveresistance to high temperaturesVSAvoidoperating cost
Core Design Contradiction:
TemperatureVSUse of energy by stationary object

Solution Approach 1:

The ceramic matrix composite material provides intrinsic thermal resistance that eliminates the need for energy-consuming water cooling systems. The material's ability to withstand extreme temperatures without degradation removes continuous operational expenses related to cooling water circulation, system maintenance, and energy consumption, significantly reducing overall operating costs.

Inventive Principle:
Principle #40Composite materials

3Temperature

If water cooling is applied to the feed injector tip, then high temperature protection is achieved, but areas of localized strain are produced resulting in cracking

Engineering Contradiction:
Improvehigh temperature protectionVSAvoidcracking resistance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The ceramic matrix composite structure inherently resists thermal shock and cracking through its fiber-reinforced architecture. The continuous fibers distribute and absorb thermal stresses uniformly throughout the material, preventing localized strain concentrations that would otherwise lead to cracking. This eliminates the thermal shock vulnerability introduced by water cooling systems while maintaining high-temperature protection.

Inventive Principle:
Principle #40Composite materials

4Productivity

If bayonet-style tubes are used to deliver high pressure flows of air/oxygen and fuel, then feed delivery is achieved, but the tubes are subjected to high pressures and high velocities causing erosion

Engineering Contradiction:
Improvefeed delivery capabilityVSAvoiderosion from high velocity flows
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The ceramic matrix composite material exhibits exceptional resistance to erosion from high-velocity coal slurry and particle flows. The interlocked fiber-matrix structure absorbs and distributes the impact forces of particles, preventing the progressive material loss that occurs with conventional metals. This allows the feed injector to maintain precise tip geometry and delivery performance even under extreme operating conditions with high-velocity flows.

Inventive Principle:
Principle #40Composite materials

5Reliability

If tip portions are replaced periodically due to cracking, corrosion, or erosion, then performance is maintained, but costly and time-consuming shutdowns are required

Engineering Contradiction:
Improveperformance maintenanceVSAvoidshutdown time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The ceramic matrix composite material simultaneously provides resistance to cracking, corrosion, and erosion that plagues conventional metal feed injector tips. By eliminating these degradation mechanisms through superior material properties, the injector maintains consistent performance throughout its service life without requiring periodic replacements, thereby avoiding costly and time-consuming system shutdowns for maintenance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design extends the lifespan of the feed injector, reduces maintenance costs, and minimizes shutdowns by enhancing creep elongation and erosion resistance, while simplifying manufacturing and operation by eliminating the need for complex cooling systems and facilitating quick tip replacements without welding.

Implementation Method 1

which provides improved resistance to high temperatures, thermal shock, corrosion, and erosion

Methodology Applied
Scientific EffectThermal shock resistance: Thermal Shock

Implementation Method 2

provides improved resistance to high temperatures, thermal shock, corrosion, and erosion

Methodology Applied
Scientific EffectCorrosion resistance: Crevice Corrosion

Implementation Method 3

provides improved resistance to high temperatures, thermal shock, corrosion, and erosion

Methodology Applied
Scientific EffectErosion resistance: Erosion

Data Source

PatentUS9644158B2Feed injector for a gasification system
Publication Date: 2017.05.09 AIR PROD & CHEM INC
  • US9644158B2 patent drawing
  • US9644158B2 patent drawing
  • US9644158B2 patent drawing

AI summary

The present disclosure provides a feed injector for a gasification system. The feed injector may include an inner tube defining an inner feed passage therein, an intermediate tube defining an intermediate feed passage therein, and an outer tube defining an outer feed passage therein. The outer tube may include an outer tube pipe portion and an outer tube tip portion attached to one another, and the outer tube tip portion may be formed of a ceramic matrix composite, a sintered Silicon Carbide, or a sintered Silicon Nitride. The present disclosure also provides a related method of operating a feed injector of a gasification system as well as a related integrated gasification combined cycle power plant.