Ceramic Glaze Additive with Silver Carrier for Antimicrobial Protection

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Solution Overview

Problem

Ceramic products, particularly sanitary ware, face challenges in achieving antimicrobial protection without compromising their appearance, as traditional antimicrobial components like bismuth and zinc cause issues such as fluidity, dripping, discoloration, and surface defects due to high firing temperatures and long firing times.

Innovation Solution

A ceramic glaze additive formulation incorporating a fritted antimicrobial composition with a silver carrier in a glass matrix, combining bismuth oxide (Bi2O3) and zinc oxide (ZnO) with flux frit, which allows for a wider range of compositions and easier integration into the glaze, reducing surface defects and energy requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional antimicrobial components (bismuth and zinc) are used in ceramic glazes, then antimicrobial protection is achieved, but the glaze exhibits increased fluidity, dripping, and surface defects due to high firing temperatures and long firing times

Engineering Contradiction:
Improveantimicrobial protectionVSAvoidglaze fluidity and dripping
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a carrier material as an intermediary substance that delivers antimicrobial components to the glaze surface. The carrier material acts as a vehicle that prevents direct interaction between bismuth/zinc and the glaze matrix, thereby reducing harmful effects like fluidity and dripping while maintaining antimicrobial functionality through controlled release or surface deposition.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the physical and chemical parameters of the antimicrobial components by changing their form (e.g., particle size, coating, or chemical compound form) and controlling their release characteristics. This allows the antimicrobial agents to remain stable at high firing temperatures and long firing times without causing excessive glaze fluidity or surface defects.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If high firing temperatures and long firing times are used for sanitary ware, then the glaze achieves desired aesthetic color and appearance, but energy consumption increases and surface defects occur

Engineering Contradiction:
Improveaesthetic color and appearanceVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by stationary object

Solution Approach 1:

The patent performs preliminary processing of the glaze formulation by pre-mixing antimicrobial components with carrier materials and preparing the glaze in advance with optimized composition. This preliminary action allows the glaze to achieve aesthetic properties and antimicrobial functionality at lower firing temperatures and shorter times, thereby reducing energy consumption while maintaining manufacturing precision.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent creates a composite glaze material combining traditional glaze components with antimicrobial agents and carrier materials in specific ratios. This composite formulation enables the glaze to achieve desired aesthetic color and appearance at reduced firing temperatures and shorter times, reducing energy consumption while maintaining surface quality and preventing defects.

Inventive Principle:
Principle #40Composite materials

3Reliability

If bismuth and zinc are added to the glaze formulation, then antimicrobial properties are achieved, but the glaze experiences discoloration and dimensional changes

Engineering Contradiction:
Improveantimicrobial propertiesVSAvoidglaze color stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses carrier materials as intermediaries that isolate bismuth and zinc from direct interaction with the glaze matrix. This intermediary approach prevents unwanted chemical reactions that cause discoloration and dimensional changes, while still allowing the antimicrobial components to function effectively on the glaze surface through controlled delivery mechanisms.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical and chemical parameters of the antimicrobial components by controlling their particle size, surface treatment, or chemical form to minimize reactions with other glaze components. This parameter optimization maintains color stability and dimensional accuracy while preserving antimicrobial functionality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation provides effective antimicrobial properties while maintaining the desired aesthetic appearance and reducing the energy and time required for firing, overcoming the limitations of traditional antimicrobial components by enhancing glaze stability and reducing surface defects.

Implementation Method 1

fritting an antimicrobial formulation in a flux frit

Methodology Applied
Scientific EffectFritting: Melting

Implementation Method 2

providing a silver carrier in a glass matrix

Methodology Applied
Scientific EffectAntimicrobial action:

Data Source

PatentUS10299483B2Ceramic additive formulation and method of making
Publication Date: 2019.05.28 MICROBAN PROD CO INC

AI summary

A method of making a ceramic glaze formulation having an antimicrobial property for use with a ceramic article. The method comprises fritting an antimicrobial formulation in a flux frit, providing least one unfritted antimicrobial component, providing a silver carrier in a glass matrix, and combining the flux frit, the at least one unfritted component, and the silver carrier in the glass matrix to form the ceramic glaze formulation. The silver carrier is combined at an addition rate based on a dry weight basis of the ceramic glaze formulation. A ceramic glaze additive formulation and ceramic glazed article are also provided.