Porous Ceramic Honeycomb Filter Pore Size Control

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Solution Overview

Problem

Diesel particulate filters face challenges in minimizing backpressure while maintaining filtration efficiency and thermal shock resistance, primarily due to the clogging of small pores by wash coatings, which increases pressure drop and hinders engine performance.

Innovation Solution

A porous ceramic honeycomb filter with an oxide-based material, such as cordierite or aluminum titanate, is designed with a controlled pore size distribution where d1 ≥ 7.0 µm, minimizing small pores and achieving a narrow pore size distribution to reduce wash-coated pressure drop and improve filtration efficiency and thermal shock resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If wash coating is applied to the filter surface to improve filtration efficiency, then catalytic activity increases, but small pores become clogged and back pressure increases

Engineering Contradiction:
Improvefiltration efficiencyVSAvoidback pressure
Core Design Contradiction:
ReliabilityVSStress or pressure

Solution Approach 1:

The invention changes the pore size parameter by ensuring d1 ≥ 7.0 μm, which prevents wash coating from clogging small pores while maintaining filtration efficiency. This parameter change resolves the contradiction by allowing catalytic coating without excessive back pressure increase.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If pore size is reduced to improve filtration efficiency, then soot capture increases, but pressure drop increases due to clogged small pores

Engineering Contradiction:
Improvefiltration efficiencyVSAvoidpressure drop
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The invention optimizes the pore size parameter by setting d1 ≥ 7.0 μm, which balances filtration efficiency with acceptable pressure drop. This parameter change ensures that pores are small enough for good filtration but large enough to avoid excessive clogging and pressure loss.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If SiC material is used to improve filtration performance, then catalytic activity increases, but cost and weight increase due to multi-component design requirements

Engineering Contradiction:
Improvefiltration performanceVSAvoidmulti-component design
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention changes the material parameter by using cordierite with d1 ≥ 7.0 μm, which provides adequate filtration performance without requiring expensive multi-component SiC designs. This parameter change simplifies the device structure and reduces cost while maintaining functionality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively minimizes wash-coated pressure increase, maintains low backpressure, and enhances filtration efficiency and thermal shock resistance, achieving a significant reduction in pressure drop while maintaining excellent filtration and heat capacity.

Implementation Method 1

a porous ceramic honeycomb filter article which exhibits a very small amount of small pores... the porous ceramic honeycomb filter article includes both a very small amount of small pores and also a narrow pore size distribution

Methodology Applied
Scientific EffectPorosity: Porosity

Data Source

PatentEP1966108B1Controlled pore size distribution porous ceramic honeycomb filter
Publication Date: 2012.01.11 CORNING INC
  • EP1966108B1 patent drawingFigure 1~2
  • EP1966108B1 patent drawingFigure 3~6
  • EP1966108B1 patent drawingFigure 7~8

AI summary

A porous ceramic honeycomb filter manufactured from an oxide-based ceramic material having a pore size distribution with d1 > 7.0 microns. Preferably, the oxide-based material is cordierite or aluminum titanate. Alternatively, the filter contains a cordierite-containing ceramic body with a narrow pore size distribution with db <1.00, wherein db = (d90 - d10) / d50. Also disclosed is a batch mixture, method and honeycomb green body made from mixture of inorganic source materials selected from the group of magnesia sources, alumina sources, and silica sources, and a pore former having a narrow particle size distribution with dps < 0.90, wherein dps = {(dp90-dp10)/dp50}. The pore former is preferably selected from a group consisting of canna starch, sago palm starch, green mung bean starch, and single-mode potato starch.