Ceramic Media Sintering for Thermal Stability

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Solution Overview

Problem

Conventional ceramic media used in chemical processing apparatuses, such as thermal oxidizers, are not cost-effectively manufactured at lower sintering temperatures and lack stability when exposed to temperatures higher than their sintering temperature, leading to potential fusion and operational issues.

Innovation Solution

Ceramic media are sintered at temperatures between 1200° C. and 1250° C., using a mixture of magnesium oxide, ball clay, and feldspar, resulting in a porous structure with a major phase of MgO, which maintains physical stability and separability even after exposure to temperatures up to 1500° C.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If ceramic media are sintered at lower temperatures to reduce manufacturing costs, then manufacturing cost decreases, but the media lacks stability when exposed to temperatures higher than sintering temperature

Engineering Contradiction:
Improvemanufacturing costVSAvoidthermal stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent uses a composite material system consisting of magnesium oxide (48-78 wt%), alumina (5-30 wt%), and silica (5-30 wt%). This composite composition enables the ceramic media to be sintered at lower temperatures (1200-1250°C) while maintaining stability at higher operating temperatures (up to 1500°C), resolving the contradiction between manufacturing cost and thermal stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameters including sintering temperature (1200-1250°C), porosity (24-38%), and particle size distribution (at least 45% of MgO particles between 30-250 microns). These parameter changes enable lower cost manufacturing while ensuring the media maintains physical stability when exposed to temperatures exceeding the sintering temperature.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If ceramic media are sintered at higher temperatures to improve thermal stability, then thermal stability improves, but manufacturing cost increases

Engineering Contradiction:
Improvethermal stabilityVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The composite material system with optimized ratios of MgO, Al2O3, and SiO2 provides thermal stability equivalent to higher temperature sintered materials, but achieves this at lower sintering temperatures (1200-1250°C versus traditional higher temperatures), thereby reducing manufacturing cost while maintaining reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

By changing the sintering temperature parameter to the optimized range of 1200-1250°C and controlling porosity at 24-38%, the patent achieves thermal stability without the need for higher temperature processing, thus avoiding increased manufacturing costs associated with high-temperature sintering.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If ceramic media are sintered at lower temperatures, then energy consumption decreases, but the media fuses when exposed to temperatures higher than sintering temperature

Engineering Contradiction:
Improveenergy consumptionVSAvoidresistance to fusion
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The composite material composition (MgO 48-78%, Al2O3 5-30%, SiO2 5-30%) creates a synergistic effect where the combination of materials provides high-temperature resistance despite lower sintering temperature, preventing fusion during thermal excursions while maintaining low energy consumption during manufacturing.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the porosity parameter to 24-38% and controls the particle size distribution (at least 45% of MgO particles between 30-250 microns), which enhances the media's ability to resist fusion at high temperatures while allowing sintering at lower temperatures that reduce energy consumption.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The media remains physically distinct and thermally stable, with a volume retention ratio of 0.9:1 to 1:1, reducing manufacturing costs and preventing fusion, thus ensuring operational integrity during thermal excursions.

Implementation Method 1

the media is then heated to a sintering temperature greater than 1200° C. and less than 1250° C.

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

The ratio of the second volume to the first volume is between 0.9:1 and 1:1

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentUS7354879B2Thermally stable ceramic media for use in high temperature environments
Publication Date: 2008.04.08 SAINT GOBAIN CERAMICS & PLASTICS INC
  • US7354879B2 patent drawing
  • US7354879B2 patent drawing
  • US7354879B2 patent drawing

AI summary

A chemical processing apparatus that utilizes a ceramic media sintered at a lower temperature than the apparatus' maximum exposure temperature is described. The media's physical and chemical properties may contribute to its thermal stability when exposed to temperatures that exceed the media's sintering temperature by at least 50° C.