Ceramic Immobilization of Platinum-Group Metals for Low-Corrosion Recovery
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Solution Overview
Problem
Conventional methods for recovering platinum-group metals are inefficient, corrosive, and environmentally harmful, with high energy and chemical agent costs, and require complex processes to separate and dissolve platinum-group metals from waste products.
Innovation Solution
A method involving the immobilization of platinum-group metals on a ceramic material by reacting a molten product containing a platinum-group metal, an alkali metal carbonate or hydroxide, and an oxide, followed by elution with an aqueous solvent to separate the platinum-group compound efficiently.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Quantity of substance
If conventional dry process is used to separate and concentrate platinum-group metal from waste product, then platinum-group metal can be extracted, but energy consumption becomes large
Solution Approach 1:
The invention changes the chemical parameters of the extraction process by using a specific molten salt composition (sodium borate-sodium carbonate system) at controlled temperatures (400-600°C). This parameter change enables direct dissolution of platinum-group metals from waste catalysts without requiring high-energy concentration steps, thereby reducing overall energy consumption while maintaining effective extraction
Solution Approach 2:
The invention extracts platinum-group metals directly from waste catalysts using the molten salt system, bypassing the conventional two-step process of separation and concentration. The molten salt directly dissolves the platinum-group metals from the waste material, achieving extraction without the energy-intensive intermediate concentration step
2Quantity of substance
If high concentration acid is used to dissolve platinum-group metal concentrate, then platinum-group metal can be dissolved, but chemical agent cost and waste liquid treatment cost become high
Solution Approach 1:
The invention introduces a molten salt intermediary (sodium borate-sodium carbonate system) that facilitates the dissolution of platinum-group metals without requiring high-concentration acids. The molten salt acts as a mediator that dissolves the metals at lower temperatures and produces a less harmful solution, thereby reducing chemical agent costs and waste liquid treatment requirements
Solution Approach 2:
The invention converts the typically harmful high-concentration acid dissolution process into a beneficial low-temperature molten salt dissolution process. The molten salt system achieves effective dissolution while producing a more environmentally friendly waste stream that requires less treatment, turning a harmful process into a beneficial one
3Quantity of substance
If aqua regia is used to dissolve platinum-group metal, then platinum-group metal can be dissolved, but equipment corrosion increases and wastewater treatment becomes complicated
Solution Approach 1:
The invention replaces the corrosive aqua regia with a molten salt intermediary (sodium borate-sodium carbonate system) that dissolves platinum-group metals without the severe corrosive effects. This intermediary substance enables effective dissolution while being much less damaging to equipment and producing simpler waste streams that are easier and less expensive to treat
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
Reduces corrosion and environmental impact while significantly lowering energy and chemical costs, enabling efficient recovery of platinum-group metals with minimal solvent contamination.
Implementation Method 1
causing a molten product of a raw material containing a platinum-group metal, a molten product of a carbonate or hydroxide of an alkali metal, a molten product of an oxide, and a ceramic material to make contact with each other so as to immobilize the platinum-group metal on the ceramic material
Implementation Method 2
elution with an aqueous solvent to separate the platinum-group compound efficiently
Data Source
AI summary
Provided is a platinum-group metal recovery method for efficiently recovering a platinum-group metal. The method for recovering a platinum-group metal includes an immobilization step of causing a molten product of a raw material containing a platinum-group metal, a molten product of a carbonate or hydroxide of an alkali metal, a molten product of an oxide, and a ceramic material to make contact with each other so as to immobilize the platinum-group metal on the ceramic material.


