Ceramic Scintillator Composition for Fast Photon-Counting X-Ray Detection

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Solution Overview

Problem

Current X-ray detectors, both direct and indirect types, struggle with high counting rates, leading to signal overlap and difficulty in measuring correct X-ray photon energy, especially in applications requiring high throughput and time resolution like X-ray CT.

Innovation Solution

A ceramic scintillator with a garnet compound composition (Lu1-xPrx)(Al1-y-zGaz)O1.5, where M includes Si, Ge, or Sn, and x, y, z satisfy specific ranges, is developed to achieve a decay time constant of 17 nsec or less, ensuring high light yield and improved response speed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional scintillator materials are used in photon-counting detectors, then high light yield is achieved, but the decay time is long causing signal pile-up at high counting rates

Engineering Contradiction:
Improveenergy resolutionVSAvoidresponse speed
Core Design Contradiction:
Measurement precisionVSSpeed

Solution Approach 1:

The invention changes the chemical composition parameters of the scintillator material by incorporating specific ratios of Lu, Pr, Al, Ga, and Si elements. This compositional parameter optimization achieves a balanced performance with decay time of 17 nsec or less while maintaining high light yield, resolving the contradiction between measurement precision and response speed.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite scintillator material combining multiple elements (Lu, Pr, Al, Ga, Si) in a garnet-type crystal structure. This composite approach leverages the advantageous properties of each element to achieve both fast decay time and high light yield, overcoming the limitations of conventional single-material scintillators.

Inventive Principle:
Principle #40Composite materials

2Power

If photoelectron multiplier tubes are used in indirect type detectors, then high multiplication factor is achieved, but the device size becomes large and pixel configuration with narrow gap is difficult

Engineering Contradiction:
Improvemultiplication factorVSAvoiddetector size
Core Design Contradiction:
PowerVSVolume of moving object

Solution Approach 1:

The invention extracts and eliminates the photoelectron multiplier tube from the detector system by using an alternative readout approach with SiPMs. This removal reduces the detector size and enables narrow gap pixel configurations while maintaining the indirect conversion architecture's advantages.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses SiPMs as a functional copy/alternative to photoelectron multiplier tubes, providing similar signal amplification capabilities in a compact form factor that enables high-resolution pixel configurations.

Inventive Principle:
Principle #26Copying

3Productivity

If silicon photomultipliers are used in indirect type detectors, then low cost and compact size are achieved, but handling high counting rates remains difficult

Engineering Contradiction:
Improvecounting rate capabilityVSAvoidsignal accuracy
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention changes the scintillator's temporal response parameters by optimizing its composition, achieving decay time of 17 nsec or less. This parameter optimization enables the SiPM-based system to handle high counting rates without signal pile-up, improving both productivity and signal accuracy.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ceramic scintillator enables X-ray detectors to handle high counting rates without signal pile-up, maintaining high sensitivity and energy resolution, thus enhancing imaging throughput and time resolution.

Implementation Method 1

a light-emitting material and a photodetector are combined

Methodology Applied
Scientific EffectScintillation: Scintillation

Implementation Method 2

converts the light into electrical signals using a photodetector

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentEP4703453A1Ceramic scintillator, photon counting-type x-ray detector, and method for producing ceramic scintillator
Publication Date: 2026.03.04 NITERRA MATERIALS CO LTD
  • EP4703453A1 patent drawingFigure 1(A)~1(C)
  • EP4703453A1 patent drawingFigure 2
  • EP4703453A1 patent drawingFigure 3

AI summary

A ceramic scintillator according to an embodiment includes a garnet compound having a composition represented by (Lu1-xPrx)a(Al1-y-zGayMz)bO1.5{a+b}, In the ceramic scintillator, M in the composition includes one kind or more of Si, Ge, and Sn, and x, y, and z respectively satisfy 0.002≤x≤0.500, 0.1≤y≤0.8, and 0.0010≤z≤0.1000.