Ceramic Circuit Substrate Bonding Layer Design

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Solution Overview

Problem

Conventional ceramic circuit substrates face durability and reliability issues due to thermal expansion differences between copper and ceramic materials, leading to copper peeling off and substrate cracking when thicker copper is used for improved heat dissipation.

Innovation Solution

The use of an active metal brazing material in bulk form, alloyed with constituent metals, forms a bonding layer with a higher ratio of active metal compound layer to ceramic substrate interface, enhancing bonding durability and thermal stress resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If the copper circuit and copper heat sink are thickened to improve heat dissipation capability, then the heat dissipation capability is improved, but the thermal expansion difference between copper and ceramic substrate increases, leading to copper peeling off and substrate cracking

Engineering Contradiction:
Improveheat dissipation capabilityVSAvoidbonding durability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The bonding layer is designed as a composite material system consisting of multiple layers with different functions: a first bonding layer containing active metal compounds (Ti, Zr) for strong chemical bonding with ceramic, a second bonding layer for metal bonding, and an intermediate layer for stress management. This composite structure resolves the contradiction by combining materials with complementary properties to simultaneously achieve strong bonding and thermal stress resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the chemical composition parameters of the bonding layer by incorporating specific active metal compounds (Ti, Zr) and controlling the ratio of different bonding materials. This parameter optimization allows the bonding layer to accommodate thermal expansion differences while maintaining strong adhesion, thus resolving the contradiction between heat dissipation and bonding durability.

Inventive Principle:
Principle #35Parameter changes

2Strength

If conventional active metal soldering is used to bond copper to ceramic substrate, then bonding is achieved, but the bonding layer has insufficient resistance to thermal stress, causing copper peeling and substrate cracking when thicker copper is used

Engineering Contradiction:
Improvebonding strengthVSAvoidthermal stress resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The bonding layer is segmented into multiple functional layers: a first bonding layer with active metal compounds for ceramic bonding, a second bonding layer for copper bonding, and an intermediate layer for stress management. This segmentation allows each layer to specialize in one function, resolving the contradiction by distributing thermal stress across multiple layers rather than concentrating it in a single bonding interface.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

An intermediate layer is introduced between the first bonding layer (bonded to ceramic) and the second bonding layer (bonded to copper). This intermediate layer acts as a mediator that gradually transitions the thermal expansion properties between the ceramic and copper sides, reducing thermal stress concentration and preventing bonding failure under thermal cycling conditions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses copper peeling off and substrate cracking under thermal stress, achieving improved durability and reliability of ceramic circuit substrates with enhanced heat dissipation capabilities.

Implementation Method 1

active metal soldering is normally applied. The active metal soldering is one aspect of bonding methods through brazing, and is a method for bonding a metal and a ceramic by using an active metal brazing material

Methodology Applied
Scientific EffectBrazing: Brazing

Implementation Method 2

the active metal in the active metal brazing material concentrates on a bonded interface between the brazing material component and the ceramic, allowing oxygen and nitrogen in the ceramic to react to exert a bonding force

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

The powder of the metals in the active metal brazing material then melts to form a bonding layer between the ceramic substrate and the copper circuit

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP3471517B1Ceramic circuit substrate and method for producing ceramic circuit substrate
Publication Date: 2024.08.21 TANAKA KIKINZOKU KOGYO KK
  • EP3471517B1 patent drawingFigure 1(a)~1(b)
  • EP3471517B1 patent drawingFigure 2~3b

AI summary

A ceramic circuit substrate according to the present invention includes a ceramic substrate, a copper circuit made of a copper-based material bonded, via a bonding layer, to a surface of the ceramic, and a copper heat sink made of the copper-based material bonded, via a bonding layer, to the other surface of the ceramic. The bonding layers each include a brazing material component including two or more kinds of metals, such as Ag, and an active metal having a predetermined concentration. The bonding layers each include a brazing material layer including the brazing material component, and an active metal compound layer containing the active metal. A ratio of a bonding area of the active metal compound layer in a bonding area of each of the bonding layers is 88% or more.