Ceramic Substrate with Tungsten Electrode for Stable Insulation

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Solution Overview

Problem

Ceramics substrates used in electrostatic chucks for semiconductor manufacturing often have insulation resistance that decreases with increasing temperature due to the presence of sintering agents, which can compromise bonding strength with conductive materials like tungsten.

Innovation Solution

A ceramics substrate with an aluminum oxide body and a sintered tungsten-based electric conductor pattern containing nickel oxide and silicon dioxide, eliminating the need for sintering agents to improve sinterability and adhesiveness while maintaining high purity and low temperature dependency of insulation resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If sintering agents (e.g., silica, magnesia, calcia, yttria) are contained in alumina ceramics to improve sinterability, then bonding strength between ceramics and tungsten conductor is achieved, but insulation resistance decreases as temperature increases

Engineering Contradiction:
Improvebonding strengthVSAvoidinsulation resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention extracts and removes sintering agents from the alumina ceramics composition to eliminate the source of temperature-dependent insulation resistance degradation. By using sintering agent-free alumina ceramics, the patent achieves stable insulation resistance across temperature ranges while maintaining bonding strength through alternative means (tungsten paste formulation and firing process optimization).

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters of the ceramics by eliminating sintering agents and instead optimizing the tungsten paste composition with specific additives. This parameter change allows the system to achieve bonding without compromising insulation resistance stability at elevated temperatures.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If sintering agent-free alumina ceramics are used to maintain low temperature dependency of insulation resistance, then bonding strength between ceramics and tungsten cannot be obtained

Engineering Contradiction:
Improveinsulation resistance stabilityVSAvoidbonding strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention introduces organic additives (cellulose, starch, or dextrin) as intermediaries in the tungsten paste formulation. These organic materials facilitate bonding between the tungsten and sintering agent-free alumina ceramics during the firing process, enabling adhesion without requiring sintering agents in the ceramics themselves, thus preserving insulation resistance stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite system where sintering agent-free alumina ceramics are combined with specially formulated tungsten paste containing organic additives. This composite approach allows the ceramics to maintain their insulating properties while the composite paste structure provides the necessary bonding mechanism during sintering.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances sinterability and adhesiveness between the ceramics and tungsten, maintaining the substrate's characteristics without sintering agents, and reduces temperature-dependent insulation resistance degradation.

Implementation Method 1

the green sheet and the electrically conductive paste are sintered simultaneously

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

it may be impossible to obtain bonding strength between the ceramics and the tungsten which serves as a conductor

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS11177152B2Ceramic substrate containing aluminum oxide and electrostatic chuck having electrode containing tungsten with oxides
Publication Date: 2021.11.16 SHINKO ELECTRIC IND CO LTD
  • US11177152B2 patent drawing
  • US11177152B2 patent drawing
  • US11177152B2 patent drawing

AI summary

A ceramics substrate includes: a substrate body; and an electric conductor patient that is provided in the substrate body. The substrate body is made of ceramics containing aluminum oxide. The electric conductor pattern is a sintered body that contains tungsten as a main component and further contains nickel oxide, aluminum oxide and silicon dioxide.