Ceramic Ultrafiltration with Ozone for WFI Production

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Solution Overview

Problem

Current methods for producing Water for Injection (WFI) are energy-intensive due to distillation requirements and fail to effectively disinfect and maintain the integrity of ultrafiltration systems against microorganisms.

Innovation Solution

A process involving pre-treatment with an ion exchanger, followed by reverse osmosis, electrodeionization, and ultrafiltration using a ceramic membrane, with ozone application for disinfection, and UV irradiation to remove ozone before subsequent stages, ensuring the system's sterility and ion reduction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If distillation process is used to produce WFI, then water purity is improved, but energy consumption increases

Engineering Contradiction:
Improvewater purityVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The water purification process is divided into multiple sequential stages: reverse osmosis for initial separation, electrodeionization for ion removal, and ultrafiltration for final purification. This segmentation allows each stage to specialize in removing specific impurities, achieving high purity without requiring energy-intensive distillation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent replaces the thermal-mechanical distillation process with a combination of membrane-based separation (reverse osmosis and ultrafiltration) and electrochemical processes (electrodeionization). This substitution eliminates the need for high-temperature heating and phase change, significantly reducing energy consumption while maintaining water purity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If conventional ultrafiltration membrane is used, then water purification is improved, but microorganism contamination risk increases

Engineering Contradiction:
Improvewater purificationVSAvoidmicroorganism contamination
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent introduces ozone (a strong oxidant) into the ultrafiltration system to continuously disinfect the water and kill microorganisms on the membrane surface. The ozone oxidizes and destroys microbial cell walls and structures, providing effective disinfection without compromising the ultrafiltration membrane's integrity or the water's purity.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Solution Approach 2:

The patent implements continuous ozone treatment throughout the ultrafiltration process, maintaining constant disinfection pressure. This continuous action ensures that microorganisms are constantly killed and prevented from accumulating on the membrane, eliminating the need for periodic cleaning and maintaining consistent water quality.

Inventive Principle:
Principle #20Continuity of useful action

3Object-affected harmful factors

If ozone is applied for disinfection in ultrafiltration, then microorganism elimination is improved, but membrane damage risk increases

Engineering Contradiction:
Improvemicroorganism eliminationVSAvoidmembrane integrity
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent carefully controls the ozone concentration, contact time, and pH levels in the ultrafiltration system. By optimizing these parameters, the system achieves effective microorganism elimination while preventing excessive oxidation that could damage the membrane. The controlled conditions ensure ozone acts as a disinfectant rather than a membrane-degrading agent.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If multiple purification stages are implemented, then water purity is improved, but device complexity increases

Engineering Contradiction:
Improvewater purityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent designs each purification stage to serve multiple functions: reverse osmosis removes both ions and suspended particles, electrodeionization targets specific ions, and ultrafiltration eliminates microorganisms while maintaining water clarity. This multi-functionality at each stage reduces the need for additional separate systems, managing overall process complexity while achieving high purity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach eliminates the need for costly distillation, effectively reduces ion content, and maintains system sterility by continuously disinfecting the ultrafiltration module and storage areas, enabling the production of high-purity WFI while preventing microorganism accumulation.

Implementation Method 1

The feed water is first subjected to reverse osmosis. Prior to reverse osmosis, the feed water undergoes pretreatment, for example, softening by an ion exchanger.

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

The feed water is first subjected to reverse osmosis.

Methodology Applied
Scientific EffectReverse osmosis: Reverse Osmosis

Implementation Method 3

After at least one reverse osmosis stage, the water is subjected to electrodeionization

Methodology Applied
Scientific EffectElectrodeionization: Electrolysis

Implementation Method 4

the water is subjected to at least one ultrafiltration stage. According to the invention, the semipermeable membrane used for ultrafiltration is a ceramic membrane.

Methodology Applied
Scientific EffectUltrafiltration: Filter (physical)

Implementation Method 5

The module where ultrafiltration takes place is continuously exposed to ozone. This disinfects and kills any microorganisms that may be present.

Methodology Applied
Scientific EffectOzone disinfection: Ozone

Implementation Method 6

UV irradiation to remove ozone before subsequent stages

Methodology Applied
Scientific EffectUV photodissociation: Photodissociation

Data Source

PatentEP3284728B1Process for the preparation of pharmaceutically usable waters, which are waters for injection and device for carrying out the process
Publication Date: 2019.10.16 RUCKER THOMAS
  • EP3284728B1 patent drawingFigure 1
  • EP3284728B1 patent drawingFigure 2
  • EP3284728B1 patent drawingFigure 3

AI summary

The invention relates to a process for producing pharmaceutically usable water (31), in particular water for injection (WFI). In this process, drinking water quality water, hereinafter referred to as feed water (30), is subjected to at least one reverse osmosis (10) and at least one ultrafiltration (20) to treat the feed water (30). The membrane used for the ultrafiltration (20) is a ceramic membrane (21), and the module in which the ultrafiltration (20) takes place is continuously exposed to ozone. The invention proposes that, after the at least one reverse osmosis (10), the water is subjected to electrodeionization (11).Furthermore, the invention relates to a device for carrying out the previously described method for producing pharmaceutically usable waters (31), wherein the invention provides that at least one reverse osmosis device (10) and at least one ultrafiltration device (20) as well as an electrodeionization device (11) are provided and that the membrane of the ultrafiltration device (20) is a ceramic membrane (21) and the ultrafiltration device (20) is exposed to ozone (Fig. 1).