Cerium-Doped Phosphor for High-Current LED Stability

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Solution Overview

Problem

Europium-doped compounds in optoelectronic components exhibit efficiency dips at high current intensities, leading to color locus instability and brightness loss, which is a challenge for achieving high color rendering index and efficient light emission in flashlights for portable devices.

Innovation Solution

An optoelectronic component using a semiconductor chip with a conversion element comprising a cerium-doped phosphor (La1-xCax)3Si6(N1-yOy)11:Ce3+ that generates white mixed light by converting primary blue radiation into secondary radiation, avoiding the inefficiencies of europium-doped materials and maintaining stability at high currents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If europium-doped phosphors are used to achieve high color rendering index (CRI>75), then color rendering is improved, but efficiency dips occur at high current intensities leading to brightness loss and color locus instability

Engineering Contradiction:
Improvecolor rendering indexVSAvoidcolor locus stability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the phosphor material by substituting lanthanum with calcium in the La3Si6N11:Ce structure, creating a new phosphor compound (La1-xCax)3Si6N11:Ce that maintains high CRI while eliminating efficiency dips at high currents

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite phosphor material combining multiple elements (La, Ca, Si, N, Ce) in a specific structure, where the composite nature provides both high color rendering and high current stability that single-element phosphors cannot achieve

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If high current intensities are applied to achieve sufficient light output for flashlight applications, then brightness is improved, but efficiency dips cause brightness loss and color instability

Engineering Contradiction:
ImprovebrightnessVSAvoidefficiency loss
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The patent modifies the phosphor's chemical composition to be more resistant to current-induced efficiency losses, allowing the component to operate at high current intensities without experiencing the typical brightness loss and maintaining stable color output

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If multiple phosphors are used to cover the visible spectrum sufficiently well, then color rendering is improved, but device complexity increases

Engineering Contradiction:
Improvespectrum coverageVSAvoidphosphor composition
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent designs a single phosphor compound (La1-xCax)3Si6N11:Ce that performs multiple functions simultaneously: it provides broad spectrum coverage for high CRI, maintains high efficiency at various current levels, and ensures color stability, replacing what would traditionally require multiple different phosphor materials

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a more reddish-shifted color locus at lower color temperatures with reduced brightness loss and increased current density, ensuring efficient and stable light emission suitable for flashlights in portable devices.

Implementation Method 1

The semiconductor chip is operated at high current intensities in continuous operation (flash)

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

The conversion element is configured to generate secondary radiation from the primary radiation

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS10629784B2Optoelectronic component, method for producing an optoelectronic component and flashlight for a portable device
Publication Date: 2020.04.21 OSRAM OLED
  • US10629784B2 patent drawing
  • US10629784B2 patent drawing
  • US10629784B2 patent drawing

AI summary

The invention relates to an optoelectronic component (100) comprising a semiconductor chip (1) for generating a primary beam in the blue spectral range, a conversion element (4) which is arranged in the beam path of the semiconductor chip (2) and is designed to generate a secondary beam from the primary beam, wherein the conversion element (4) comprises at least one first luminescent material (9) used as a conversion material, the first luminescent material (9) being (La1-xCax)3Si6(N1-yOy)11:Ce3+ with 0≤x≤1 and 0<y≤1, wherein a total beam (G) emerging from the component (100) is white mixed light.