Cerium Oxide Nucleic Acid Detection Sensitivity

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Solution Overview

Problem

Current nucleic acid detection methods require complex operations or organic solvents, and existing methods without these limitations, such as using magnetic inorganic components, suffer from reduced nucleic acid purity due to elution of inorganic components, and lack sensitivity in detecting nucleic acids with higher order structures.

Innovation Solution

A method utilizing cerium oxide as a support with carboxylic acid to adsorb and elute nucleic acids, enhancing the sensitivity of detection, particularly for nucleic acids with higher order structures, through a hybridization or amplification reaction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If magnetic inorganic components are used to collect nucleic acid without organic solvents, then the operation complexity is reduced, but the purity of collected nucleic acid decreases due to elution of inorganic components

Engineering Contradiction:
Improveoperation complexityVSAvoidnucleic acid purity
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent uses a composite material consisting of iron oxide particles coated with silica. The iron oxide core provides magnetic properties for easy separation without organic solvents, while the silica coating prevents elution of inorganic components into the collecting solution, thereby maintaining nucleic acid purity. This composite structure resolves the contradiction between ease of operation and manufacturing precision.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If conventional collection methods are used, then nucleic acid purity is maintained, but the detection sensitivity for nucleic acids with higher order structures is insufficient

Engineering Contradiction:
Improvenucleic acid purityVSAvoiddetection sensitivity
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The patent changes the physical and chemical parameters of the collection method by using magnetic silica particles with specific surface properties. This allows efficient adsorption of nucleic acids including those with higher order structures, and enables their collection in a form that maintains both purity and high detection sensitivity for downstream applications like PCR and hybridization.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If phenol-chloroform extraction is used to collect nucleic acid, then the purity of collected nucleic acid is improved, but the operation complexity increases and organic solvents are required

Engineering Contradiction:
Improvenucleic acid purityVSAvoidoperation complexity
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The patent replaces the chemical extraction system (phenol-chloroform) with a magnetic separation system. Magnetic silica particles are used to adsorb nucleic acids directly from the sample, and a magnetic field is applied for separation. This mechanical/magnetic approach eliminates the need for organic solvents and complex multiple-step procedures, while maintaining high purity and improving ease of operation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method improves the sensitivity of nucleic acid detection, allowing for the effective collection and analysis of nucleic acids with higher order structures without complex operations or organic solvents, achieving higher PCR and hybridization efficiencies.

Implementation Method 1

mixing a solution containing a carboxylic acid and/or a salt thereof, a cerium oxide support and a sample containing a nucleic acid to adsorb the nucleic acid to the cerium oxide support

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

separating the cerium oxide support on which the nucleic acid was adsorbed from the mixture obtained in the step a)

Methodology Applied
Scientific EffectCentrifugation: Centrifuge

Data Source

PatentUS11492655B2Method of detecting a nucleic acid
Publication Date: 2022.11.08 TORAY INDUSTRIES INC

AI summary

A method of detecting a nucleic acid including a) mixing a solution containing a carboxylic acid and/or a salt thereof, a cerium oxide support and a sample containing a nucleic acid to adsorb said nucleic acid to said cerium oxide support, b) separating said cerium oxide support on which said nucleic acid was adsorbed from the mixture obtained in a), c) collecting said nucleic acid by adding an eluent to said cerium oxide support on which said nucleic acid was adsorbed and separated in b), and d) detecting said nucleic acid collected in c) by a hybridization reaction or a nucleic acid amplification reaction.